DICP OpenIR
Mild Michael Addition of Glycine Imines to Aromatic Nitroalkenes Catalyzed by DBU with LiOTf as an Additive
Li, Wei1; Liu, Han1; Du, Da-Ming1,2
KeywordMichael Addition Nitroalkene Catalysis Amino Acids Dbu
Source PublicationSYNLETT
2009-04-01
DOI10.1055/s-0028-1088210
Issue6Pages:925-928
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordPHASE-TRANSFER CATALYSIS ; ALPHA-AMINO-ACIDS ; FRIEDEL-CRAFTS ALKYLATION ; ENANTIOSELECTIVE SYNTHESIS ; AZOMETHINE YLIDES ; ETHYL N-(DIPHENYLMETHYLENE)GLYCINATE ; 1,3-DIPOLAR CYCLOADDITION ; DERIVATIVES ; COMPLEXES ; BIS(OXAZOLINE)
AbstractA mild Michael addition of glycine imines to aromatic-nitroalkenes catalyzed by 10 mol% DBU with LiOTf as an additive was developed. In most cases, the products could be obtained in good yields (up to 96%) with moderate to good diastereoselectivities (up to 10:1). The selectivity for syn adduct can be reversed to anti when the R group of glycine imines was changed from methyl or ethyl to tert-butyl.
Language英语
WOS IDWOS:000266069100008
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141608
Collection中国科学院大连化学物理研究所
Affiliation1.Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, BNLMS, Beijing 100871, Peoples R China
2.Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China
Recommended Citation
GB/T 7714
Li, Wei,Liu, Han,Du, Da-Ming. Mild Michael Addition of Glycine Imines to Aromatic Nitroalkenes Catalyzed by DBU with LiOTf as an Additive[J]. SYNLETT,2009(6):925-928.
APA Li, Wei,Liu, Han,&Du, Da-Ming.(2009).Mild Michael Addition of Glycine Imines to Aromatic Nitroalkenes Catalyzed by DBU with LiOTf as an Additive.SYNLETT(6),925-928.
MLA Li, Wei,et al."Mild Michael Addition of Glycine Imines to Aromatic Nitroalkenes Catalyzed by DBU with LiOTf as an Additive".SYNLETT .6(2009):925-928.
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