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Rh(I)-Catalyzed [(3+2)+1] Cycloaddition of 1-Yne/Ene-vinylcyclopropanes and CO: Homologous Pauson-Khand Reaction and Total Synthesis of (+/-)-alpha-Agarofuran
Jiao, Lei; Lin, Mu; Zhuo, Lian-Gang; Yu, Zhi-Xiang
刊名ORGANIC LETTERS
2010-06-04
DOI10.1021/ol100625e
12期:11页:2528-2531
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]DIELS-ALDER REACTIONS ; DONOR-ACCEPTOR CYCLOPROPANES ; ALPHA-AGAROFURAN ; ENE-VINYLCYCLOPROPANES ; BETA-AGAROFURAN ; MECHANISM ; ALKYNES ; SESQUITERPENOIDS ; 1,3-DIENES ; ALDEHYDES
英文摘要A novel Rh(I)-catalyzed [(3 + 2) + 1] cycloaddition, which can be regarded as a homologous Pauson-Khand reaction, was developed to synthesize bicyclic cyclohexenones and cyclohexanones, enabling a new approach for synthesis of six-membered carbocycles ubiquitously found in natural products and pharmaceutics. The significance of the Rh-catalyzed [(3 + 2) + 1] cycloaddition has been demonstrated by the total synthesis of a furanoid sesquiterpene natural product, a-agarofuran, in which the bicyclic skeleton was constructed by the [(3 + 2) + 1] reaction of 1-yne-VCP and CO.
语种英语
WOS记录号WOS:000278062600023
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141653
专题中国科学院大连化学物理研究所
作者单位Peking Univ, BNLMS, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China
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GB/T 7714
Jiao, Lei,Lin, Mu,Zhuo, Lian-Gang,et al. Rh(I)-Catalyzed [(3+2)+1] Cycloaddition of 1-Yne/Ene-vinylcyclopropanes and CO: Homologous Pauson-Khand Reaction and Total Synthesis of (+/-)-alpha-Agarofuran[J]. ORGANIC LETTERS,2010,12(11):2528-2531.
APA Jiao, Lei,Lin, Mu,Zhuo, Lian-Gang,&Yu, Zhi-Xiang.(2010).Rh(I)-Catalyzed [(3+2)+1] Cycloaddition of 1-Yne/Ene-vinylcyclopropanes and CO: Homologous Pauson-Khand Reaction and Total Synthesis of (+/-)-alpha-Agarofuran.ORGANIC LETTERS,12(11),2528-2531.
MLA Jiao, Lei,et al."Rh(I)-Catalyzed [(3+2)+1] Cycloaddition of 1-Yne/Ene-vinylcyclopropanes and CO: Homologous Pauson-Khand Reaction and Total Synthesis of (+/-)-alpha-Agarofuran".ORGANIC LETTERS 12.11(2010):2528-2531.
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