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题名: Activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate [EMINI][TCB] using gas-liquid chromatography
作者: Yan, Pei-Fang1;  Yang, Miao1;  Liu, Xiu-Mei1;  Wang, Chang1;  Tan, Zhi-Cheng1, 2;  Welz-Biermann, Urs1
关键词: Ionic liquid ;  Gas-liquid chromatography ;  Activity coefficient at infinite dilution ;  Partial molar excess enthalpy at infinite dilution
刊名: JOURNAL OF CHEMICAL THERMODYNAMICS
发表日期: 2010-06-01
DOI: 10.1016/j.jct.2010.02.006
卷: 42, 期:6, 页:817-822
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Thermodynamics ;  Chemistry, Physical
研究领域[WOS]: Thermodynamics ;  Chemistry
英文摘要: The activity coefficients at infinite dilution, gamma(infinity)(i), for both polar and non-polar solutes in the ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate [EMIM][TCB] have been determined by gas liquid chromatography at the temperatures from (303 to 343) K. The partial molar excess enthalpies at infinite dilution of the H(i)(E,infinity) solutes in the ionic liquid were also calculated from the temperature dependence of the gamma(infinity)(i) values. The selectivity for the hexane/benzene and cyclohexane/benzene separation problems was calculated from experimental infinite dilution activity coefficient values and compared to the other ionic liquids, taken from the recent literature. (C) 2010 Elsevier Ltd. All rights reserved.
关键词[WOS]: SENSITIZED SOLAR-CELLS ;  THERMODYNAMIC PROPERTIES ;  VIRIAL COEFFICIENTS ;  NONPOLAR SOLUTES ;  ALKYL BENZENES ;  POLAR SOLUTES ;  MIXTURES ;  HYDROCARBONS ;  ALCOHOLS ;  ALDEHYDES
语种: 英语
WOS记录号: WOS:000277647000019
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141663
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China

Recommended Citation:
Yan, Pei-Fang,Yang, Miao,Liu, Xiu-Mei,et al. Activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate [EMINI][TCB] using gas-liquid chromatography[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2010,42(6):817-822.
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