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Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms
Zhang, Zeng-Guang; Xu, Hong-Guang; Feng, Yuan; Zheng, Weijun
刊名JOURNAL OF CHEMICAL PHYSICS
2010-04-28
DOI10.1063/1.3374431
132期:16
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Physics, Atomic, Molecular & Chemical
研究领域[WOS]Physics
关键词[WOS]CHARGED ALUMINUM CLUSTERS ; PHOTOELECTRON-SPECTROSCOPY ; ANIONS ; SEARCH ; METAL
英文摘要We investigated AlnS- (n=3-15) and AlnS2- (n=7-15) clusters with mass spectrometry and photoelectron spectroscopy. We found that Al-13 is relatively robust when it reacts with sulfur atoms, indicating that it has some superatomic character. However, Al-13 cannot be simply considered as a superatom when it interacts with sulfur due to the following reasons: Al-13's icosahedral structure has been distorted slightly by sulfur atoms; the vertical detachment energies and adiabatic detachment energies of Al13S- and Al13S2- clusters are not significantly different from those of their neighboring clusters; and the charge distributions in Al13S- and Al13S2- do not necessarily associate with superatomic behavior of Al-13. (C) 2010 American Institute of Physics. [doi: 10.1063/1.3374431]
语种英语
WOS记录号WOS:000277241500003
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141679
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China
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Zhang, Zeng-Guang,Xu, Hong-Guang,Feng, Yuan,et al. Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms[J]. JOURNAL OF CHEMICAL PHYSICS,2010,132(16).
APA Zhang, Zeng-Guang,Xu, Hong-Guang,Feng, Yuan,&Zheng, Weijun.(2010).Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms.JOURNAL OF CHEMICAL PHYSICS,132(16).
MLA Zhang, Zeng-Guang,et al."Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms".JOURNAL OF CHEMICAL PHYSICS 132.16(2010).
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