中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms
作者: Zhang, Zeng-Guang1;  Xu, Hong-Guang1;  Feng, Yuan1;  Zheng, Weijun1
刊名: JOURNAL OF CHEMICAL PHYSICS
发表日期: 2010-04-28
DOI: 10.1063/1.3374431
卷: 132, 期:16
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Physics
英文摘要: We investigated AlnS- (n=3-15) and AlnS2- (n=7-15) clusters with mass spectrometry and photoelectron spectroscopy. We found that Al-13 is relatively robust when it reacts with sulfur atoms, indicating that it has some superatomic character. However, Al-13 cannot be simply considered as a superatom when it interacts with sulfur due to the following reasons: Al-13's icosahedral structure has been distorted slightly by sulfur atoms; the vertical detachment energies and adiabatic detachment energies of Al13S- and Al13S2- clusters are not significantly different from those of their neighboring clusters; and the charge distributions in Al13S- and Al13S2- do not necessarily associate with superatomic behavior of Al-13. (C) 2010 American Institute of Physics. [doi: 10.1063/1.3374431]
关键词[WOS]: CHARGED ALUMINUM CLUSTERS ;  PHOTOELECTRON-SPECTROSCOPY ;  ANIONS ;  SEARCH ;  METAL
语种: 英语
WOS记录号: WOS:000277241500003
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141679
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China

Recommended Citation:
Zhang, Zeng-Guang,Xu, Hong-Guang,Feng, Yuan,et al. Communications: Investigation of the superatomic character of Al-13 via its interaction with sulfur atoms[J]. JOURNAL OF CHEMICAL PHYSICS,2010,132(16).
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Zhang, Zeng-Guang]'s Articles
 [Xu, Hong-Guang]'s Articles
 [Feng, Yuan]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Zhang, Zeng-Guang]‘s Articles
 [Xu, Hong-Guang]‘s Articles
 [Feng, Yuan]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace