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题名: Formal total synthesis of (+/-)-hirsutic acid C using the tandem Rh(I)-catalyzed [(5+2)+1] cycloaddition/aldol reaction
作者: Yuan, Changxia1;  Jiao, Lei1;  Yu, Zhi-Xiang1
刊名: TETRAHEDRON LETTERS
发表日期: 2010-10-27
DOI: 10.1016/j.tetlet.2010.08.028
卷: 51, 期:43, 页:5674-5676
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A concise formal total synthesis of the linear triquinane natural product (+/-)-hirsutic acid C has been achieved. This synthesis features a tandem Rh(I)-catalyzed [(5+2)+1] cycloaddition/aldol reaction as the key step to build the triquinane skeleton. (C) 2010 Elsevier Ltd. All rights reserved.
关键词[WOS]: STEREOCONTROLLED TOTAL-SYNTHESIS ;  SIGMATROPIC 1,2-ACYL SHIFT ;  (+)-HIRSUTIC ACID ;  ENE-VINYLCYCLOPROPANES ;  (-)-COMPLICATIC ACID ;  COMPLICATIC ACID ;  CARBOCYCLES ;  METATHESIS ;  EFFICIENT
语种: 英语
WOS记录号: WOS:000283385900011
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141711
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Coll Chem, Beijing 100871, Peoples R China

Recommended Citation:
Yuan, Changxia,Jiao, Lei,Yu, Zhi-Xiang. Formal total synthesis of (+/-)-hirsutic acid C using the tandem Rh(I)-catalyzed [(5+2)+1] cycloaddition/aldol reaction[J]. TETRAHEDRON LETTERS,2010,51(43):5674-5676.
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