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题名: Heat capacities and thermodynamic properties of one manganese-based MOFs
作者: Song, Li-Fang3, 4;  Jiang, Chun-Hong3, 4;  Jiao, Cheng-Li3, 4;  Zhang, Jian3;  Sun, Li-Xian3;  Xu, Fen5;  Jiao, Qing-Zhu5;  Xing, Yong-Heng5;  Du, Yong6;  Cao, Zhong7;  Huang, Feng-Lei8
关键词: Manganese ;  Metal-organic framework ;  Molar heat capacity ;  TGA ;  TMDSC
刊名: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
发表日期: 2010-12-01
DOI: 10.1007/s10973-010-0808-7
卷: 102, 期:3, 页:1161-1166
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Analytical ;  Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: A metal-organic framework [Mn(4,4'-bipy)(1,3-BDC)] (n) (MnMOF, 1,3-BDC = 1,3-benzene dicarboxylate, 4,4'-bipy = 4,4'-bipyridine) has been synthesized hydrothermally and characterized by single crystal XRD and FT-IR spectrum. The low-temperature molar heat capacities of MnMOF were measured by temperature-modulated differential scanning calorimetry for the first time. The thermodynamic parameters such as entropy and enthalpy relative to reference temperature 298.15 K were derived based on the above molar heat capacity data. Moreover, the thermal stability and the decomposition mechanism of MnMOF were investigated by thermogravimetry analysis-mass spectrometer. A two-stage mass loss was observed in air flow. MS curves indicated that the gas products of oxidative degradation were H2O, CO2, NO, and NO2.
关键词[WOS]: DIFFERENTIAL SCANNING CALORIMETRY ;  METAL-ORGANIC FRAMEWORKS
语种: 英语
WOS记录号: WOS:000284433000045
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141713
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Dalian Inst Chem Phys, Chinese Acad Sci, Mat & Thermochemistry Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
4.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
5.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
6.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
7.Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha 410076, Hunan, Peoples R China
8.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China

Recommended Citation:
Song, Li-Fang,Jiang, Chun-Hong,Jiao, Cheng-Li,et al. Heat capacities and thermodynamic properties of one manganese-based MOFs[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2010,102(3):1161-1166.
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