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Heat capacities and thermodynamic properties of one manganese-based MOFs
Song, Li-Fang3,4; Jiang, Chun-Hong3,4; Jiao, Cheng-Li3,4; Zhang, Jian3; Sun, Li-Xian3; Xu, Fen5; Jiao, Qing-Zhu5; Xing, Yong-Heng5; Du, Yong6; Cao, Zhong7; Huang, Feng-Lei8
KeywordManganese Metal-organic Framework Molar Heat Capacity Tga Tmdsc
Source PublicationJOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
2010-12-01
DOI10.1007/s10973-010-0808-7
Volume102Issue:3Pages:1161-1166
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Analytical ; Chemistry, Physical
WOS Research AreaChemistry
WOS KeywordDIFFERENTIAL SCANNING CALORIMETRY ; METAL-ORGANIC FRAMEWORKS
AbstractA metal-organic framework [Mn(4,4'-bipy)(1,3-BDC)] (n) (MnMOF, 1,3-BDC = 1,3-benzene dicarboxylate, 4,4'-bipy = 4,4'-bipyridine) has been synthesized hydrothermally and characterized by single crystal XRD and FT-IR spectrum. The low-temperature molar heat capacities of MnMOF were measured by temperature-modulated differential scanning calorimetry for the first time. The thermodynamic parameters such as entropy and enthalpy relative to reference temperature 298.15 K were derived based on the above molar heat capacity data. Moreover, the thermal stability and the decomposition mechanism of MnMOF were investigated by thermogravimetry analysis-mass spectrometer. A two-stage mass loss was observed in air flow. MS curves indicated that the gas products of oxidative degradation were H2O, CO2, NO, and NO2.
Language英语
WOS IDWOS:000284433000045
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141713
Collection中国科学院大连化学物理研究所
Affiliation1.Dalian Inst Chem Phys, Chinese Acad Sci, Mat & Thermochemistry Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
4.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
5.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
6.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
7.Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha 410076, Hunan, Peoples R China
8.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China
Recommended Citation
GB/T 7714
Song, Li-Fang,Jiang, Chun-Hong,Jiao, Cheng-Li,et al. Heat capacities and thermodynamic properties of one manganese-based MOFs[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2010,102(3):1161-1166.
APA Song, Li-Fang.,Jiang, Chun-Hong.,Jiao, Cheng-Li.,Zhang, Jian.,Sun, Li-Xian.,...&Huang, Feng-Lei.(2010).Heat capacities and thermodynamic properties of one manganese-based MOFs.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,102(3),1161-1166.
MLA Song, Li-Fang,et al."Heat capacities and thermodynamic properties of one manganese-based MOFs".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 102.3(2010):1161-1166.
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