中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Transfer Dehydrogenation of 1-Octanol to 1-Octanal over Cu/MgO Catalyst: Effect of Cu Particle Size
作者: Shi Ruijuan1;  Wang Fei1;  Mu Xiaoling1;  Ta Na1;  Li Yong1;  Huang Xiumin1;  Shen Wenjie1
关键词: copper ;  magnesia ;  particle size ;  transfer dehydrogenation ;  1-octanol ;  1-octanal
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2010-06-01
DOI: 10.1016/S1872-2067(09)60077-2
卷: 31, 期:6, 页:626-630
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: Cu/MgO catalysts with different Cu particle sizes were prepared by a precipitation-deposition method and investigated for their activity in the transfer dehydrogenation of alcohols to carbonyl compounds. They were highly active for the conversion of primary aliphatic alcohols, e.g. 1-octanol. With increasing Cu particle size from 4.6 to 7.4 nm, the aldehyde yield decreased from 65% 10 55%, which showed a size effect. The copper particle abstracted an alpha-hydrogen from the reactive alkoxide intermediate formed on the surface of MgO and simultaneously catalyzed the hydrogenation of styrene.
关键词[WOS]: ENVIRONMENTALLY BENIGN OXIDATION ;  FREE ALCOHOL DEHYDROGENATION ;  SECONDARY ALCOHOLS ;  PALLADIUM ;  HYDROTALCITE ;  CU/AL2O3 ;  ACCEPTOR ;  OXIDES
语种: 英语
WOS记录号: WOS:000279808000005
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141745
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Shi Ruijuan,Wang Fei,Mu Xiaoling,et al. Transfer Dehydrogenation of 1-Octanol to 1-Octanal over Cu/MgO Catalyst: Effect of Cu Particle Size[J]. CHINESE JOURNAL OF CATALYSIS,2010,31(6):626-630.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Shi Ruijuan]'s Articles
 [Wang Fei]'s Articles
 [Mu Xiaoling]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Shi Ruijuan]‘s Articles
 [Wang Fei]‘s Articles
 [Mu Xiaoling]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace