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题名: UV Raman Spectroscopic Studies on Active Sites and Synthesis Mechanisms of Transition Metal-Containing Microporous and Mesoporous Materials
作者: Fan, Fengtao1, 2;  Feng, Zhaochi1;  Li, Can1
刊名: ACCOUNTS OF CHEMICAL RESEARCH
发表日期: 2010-03-01
DOI: 10.1021/ar900210g
卷: 43, 期:3, 页:378-387
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Microporous and mesoporous materials are widely used as catalysts and catalyst supports. Although the incorporation of transition metal ions into the framework of these materials (by isomorphous substitution of Al and Si) is an effective means of creating novel catalytic activity, the characterization of the transition metal species within these materials is difficult. Both the low concentration of the highly dispersed transition metal and the coexistence of extraframework transition metal species present clear challenges. Moreover, the synthetic mechanisms that operate under the highly inhomogeneous conditions of hydrothermal synthesis are far from well understood.
关键词[WOS]: RAY-POWDER DIFFRACTION ;  MOLECULAR-SIEVES ;  CRYSTALLIZATION MECHANISM ;  HYDROTHERMAL CONDITIONS ;  TITANIUM SILICALITE-1 ;  PHASE-TRANSFORMATION ;  CATALYTIC-PROPERTIES ;  TS-1 ZEOLITE ;  FRAMEWORK ;  GLASSES
语种: 英语
WOS记录号: WOS:000275820900003
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141754
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Dalian 116023, Peoples R China

Recommended Citation:
Fan, Fengtao,Feng, Zhaochi,Li, Can. UV Raman Spectroscopic Studies on Active Sites and Synthesis Mechanisms of Transition Metal-Containing Microporous and Mesoporous Materials[J]. ACCOUNTS OF CHEMICAL RESEARCH,2010,43(3):378-387.
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