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题名: Synthesis of 2-Pyridones and Iminoesters via Rh(III)-Catalyzed Oxidative Coupling between Acrylamides and Alkynes
作者: Su, Yan1;  Zhao, Miao1;  Han, Keli1;  Song, Guoyong1;  Li, Xingwei1
刊名: ORGANIC LETTERS
发表日期: 2010-12-03
DOI: 10.1021/ol102306c
卷: 12, 期:23, 页:5462-5465
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Catalytic oxidative coupling between acrylamides and alkynes was achieved using 0.5 mol % loading of [RhCp*Cl-2](2) with Cu(OAc)(2) as an oxidant. 2-Pyridones, iminoesters, and substituted indoles could be obtained as a result of the electronic and steric effects of the substituents in the acrylamides.
关键词[WOS]: H BOND-CLEAVAGE ;  C-H ;  2+2+2 CYCLOADDITION ;  CATALYZED CYCLOISOMERIZATION ;  RHODIUM CATALYSIS ;  INTERNAL ALKYNES ;  O BOND ;  ISOCYANATES ;  DERIVATIVES ;  ACTIVATION
语种: 英语
WOS记录号: WOS:000284555600027
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141774
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Su, Yan,Zhao, Miao,Han, Keli,et al. Synthesis of 2-Pyridones and Iminoesters via Rh(III)-Catalyzed Oxidative Coupling between Acrylamides and Alkynes[J]. ORGANIC LETTERS,2010,12(23):5462-5465.
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