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题名: 1,4-Dilithio-1,3-dienes: Reaction and Synthetic Applications
作者: Xi, Zhenfeng
刊名: ACCOUNTS OF CHEMICAL RESEARCH
发表日期: 2010-10-01
DOI: 10.1021/ar1000583
卷: 43, 期:10, 页:1342-1351
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The development of organometallic reagents remains one of the most important frontiers in synthetic chemistry. Commonly used organometallic reagents (such as RLi and RMgBr) are typically monometallic compounds, although they aggregate in many cases. When two carbon-metal bonds are in the same molecule in close proximity, however, these two carbon-metal moieties may exhibit novel reactivity. In this Account, we outline our work on new reactions and synthetic applications of the organo-dilithio reagents 1,4-dilithio-1,3-butadienes.
关键词[WOS]: STRUCTURAL-CHARACTERIZATION ;  CYCLOPENTADIENE DERIVATIVES ;  SKELETAL REARRANGEMENT ;  EFFICIENT SYNTHESIS ;  FACILE SYNTHESIS ;  LITHIO SILOLES ;  REAGENTS ;  1,4-DILITHIOBUTADIENES ;  DILITHIOBUTADIENES ;  CYCLOADDITION
语种: 英语
WOS记录号: WOS:000283109400005
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141798
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,BNLMS, Beijing 100871, Peoples R China

Recommended Citation:
Xi, Zhenfeng. 1,4-Dilithio-1,3-dienes: Reaction and Synthetic Applications[J]. ACCOUNTS OF CHEMICAL RESEARCH,2010,43(10):1342-1351.
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