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题名: Oxidation of Benzene to Phenol by Dioxygen over Vanadium Oxide Nano-Plate
作者: Gao, Xiaohan1;  Lv, Xuechuan1;  Xu, Jie2
刊名: KINETICS AND CATALYSIS
发表日期: 2010-06-01
DOI: 10.1134/S0023158410030110
卷: 51, 期:3, 页:394-397
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Direct oxidation of benzene to phenol with dioxygen is an attractive and challenging subject. V(4+) vanadium species play an important role in the reaction. Nano vanadium oxide which consists mainly of the quadrivalence vanadium species was synthesized via hydrothermal method and used to catalyze the reaction without addition of reducing reagent. Investigations about performances of catalysts show that 3.7% conversion of benzene and nearly 100% selectivity of phenol are given over the fresh catalyst VO-N-A. Morphology observations display that the VO-N-A is made of nano-plate. Thermogravimetric curve illuminates that the catalyst is stable under the reaction temperature.
关键词[WOS]: SELECTIVE HYDROXYLATION ;  ACETIC-ACID ;  ZEOLITES ;  CATALYST ;  POLYOXOVANADATES ;  SPECTROSCOPY ;  OXYGEN ;  IRON ;  V2O5 ;  VO2
语种: 英语
WOS记录号: WOS:000281104600011
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141810
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Liaoning Shihua Univ, Sch Chem & Mat Sci, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Beijing 100864, Peoples R China

Recommended Citation:
Gao, Xiaohan,Lv, Xuechuan,Xu, Jie. Oxidation of Benzene to Phenol by Dioxygen over Vanadium Oxide Nano-Plate[J]. KINETICS AND CATALYSIS,2010,51(3):394-397.
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