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题名: Physicochemical Properties of an Ionic Liquid [C(2)mim][B(CN)(4)]
作者: Tong, Jing2;  Liu, Qing-Shan1;  Kong, Yu-Xia2;  Fang, Da-Wei2;  Welz-Biermann, Urs1;  Yang, Jia-Zhen2
刊名: JOURNAL OF CHEMICAL AND ENGINEERING DATA
发表日期: 2010-09-01
DOI: 10.1021/je100228t
卷: 55, 期:9, 页:3693-3696
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Multidisciplinary ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: The density and surface tension of the ionic liquid (IL) [C(2)mim][B(CN)(4)] (1-ethyl-3-methylimidazolium tetracyanoborate) were measured in a temperature range from (283.15 to 338.15) K. In terms of Glasser's semiempirical relation of ILs, the standard molar entropy and the lattice energy of the homologous series of ILs [C(n)mim][B(CN)(4)] were estimated, respectively. Using Kabo's method and Rebelo's method, the molar enthalpy of vaporization of [C(2)mim][B(CN)(4)], Delta H-g(I)m(0) (298 K), at 298 K, and Delta H-g(I)m(0) (T-b), at hypothetical normal boiling point, T-b = 680 K, was estimated, respectively. According to the interstice model, the thermal expansion coefficient of [C(2)mim][B(CN)(4)], alpha = 4.77.10(-4) K-1, was estimated and was in good agreement with experimental value.
关键词[WOS]: SURFACE-TENSION ;  TEMPERATURE ;  EFFICIENT ;  DENSITY
语种: 英语
WOS记录号: WOS:000281567000126
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141826
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China
2.Liaoning Univ, Key Lab Green Synth & Preparat Chem Adv Mat, Shenyang 110036, Peoples R China

Recommended Citation:
Tong, Jing,Liu, Qing-Shan,Kong, Yu-Xia,et al. Physicochemical Properties of an Ionic Liquid [C(2)mim][B(CN)(4)][J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2010,55(9):3693-3696.
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