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QUANTITATIVE MEASUREMENTS OF VIBRATIONAL RELAXATION RATES IN SUPERSONIC JETS OF I-2 B(nu '=43) STATE
Ma Zhiliu; Huang Ruiping
刊名ACTA PHYSICO-CHIMICA SINICA
1990
DOI10.3866/PKU.WHXB19900105
6期:1页:23-31
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
英文摘要A LIF technique that employs a varying view field has been developed to give quantitative measurement for the vibrational relaxation rates of I-2 B(nu ' = 43) state in supersonic jets. The data for Ar, N-2 and CO are obtained for the first time. The results have shown that the measured vibrational relaxation rates in cold jets bear an inverse tempeature dependence. For He and H-2 carrier gases, the dominant relaxation process is the usual Delta nu = -1 process. For Ar, N-2 and CO, however, the most probable relaxation pathway is no longer Delta nu = -1 process, which apparently violates the energy gap law. These observations are adequately explained by a metastable complex formation mechanism.
语种英语
WOS记录号WOS:000207572600005
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被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141840
专题中国科学院大连化学物理研究所
作者单位Acad Sinica, Dalian Inst Chem Phys, Dalian, Peoples R China
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GB/T 7714
Ma Zhiliu,Huang Ruiping. QUANTITATIVE MEASUREMENTS OF VIBRATIONAL RELAXATION RATES IN SUPERSONIC JETS OF I-2 B(nu '=43) STATE[J]. ACTA PHYSICO-CHIMICA SINICA,1990,6(1):23-31.
APA Ma Zhiliu,&Huang Ruiping.(1990).QUANTITATIVE MEASUREMENTS OF VIBRATIONAL RELAXATION RATES IN SUPERSONIC JETS OF I-2 B(nu '=43) STATE.ACTA PHYSICO-CHIMICA SINICA,6(1),23-31.
MLA Ma Zhiliu,et al."QUANTITATIVE MEASUREMENTS OF VIBRATIONAL RELAXATION RATES IN SUPERSONIC JETS OF I-2 B(nu '=43) STATE".ACTA PHYSICO-CHIMICA SINICA 6.1(1990):23-31.
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