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Hydrogen Storage Properties of Ca(BH4)(2)-LiNH2 System
Chu, Hailiang; Xiong, Zhitao; Wu, Guotao; Guo, Jianping; Zheng, Xueli; He, Teng; Wu, Chengzhang; Chen, Ping
关键词Borates Calcium Hydrides Hydrogen Lithium
刊名CHEMISTRY-AN ASIAN JOURNAL
2010
DOI10.1002/asia.200900677
5期:7页:1594-1599
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]N-H SYSTEM ; VIBRATIONAL-SPECTRA ; AMMONIA BORANE ; DESORPTION ; RELEASE ; PHASE ; LIB0.33N0.67H2.67 ; BOROHYDRIDES ; DIFFRACTION ; MG(BH4)(2)
英文摘要Ca(BH4)(2) is one of the promising candidates for hydrogen storage materials because of its high gravimetric and volumetric hydrogen capacity. However, its high dehydrogenation temperature and limited reversibility has been a hurdle for its practical applications. In an effort to overcome these barriers and to adjust the thermal stability, we make a composite system Ca(BH4)(2)-LiNH2. Interaction of Ca(BH4)(2) and LiNH2 leads to decreased dehydrogenation temperatures and increased hydrogen desorption capacity in comparison to pristine Ca(BH4)(2). More than 7 wt % of hydrogen can be detached at a temperature as low as approximately 178 degrees C from the cobalt-catalyzed Ca(BH4)(2)-4LiNH(2) system.
语种英语
WOS记录号WOS:000280869300011
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141851
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Chu, Hailiang,Xiong, Zhitao,Wu, Guotao,et al. Hydrogen Storage Properties of Ca(BH4)(2)-LiNH2 System[J]. CHEMISTRY-AN ASIAN JOURNAL,2010,5(7):1594-1599.
APA Chu, Hailiang.,Xiong, Zhitao.,Wu, Guotao.,Guo, Jianping.,Zheng, Xueli.,...&Chen, Ping.(2010).Hydrogen Storage Properties of Ca(BH4)(2)-LiNH2 System.CHEMISTRY-AN ASIAN JOURNAL,5(7),1594-1599.
MLA Chu, Hailiang,et al."Hydrogen Storage Properties of Ca(BH4)(2)-LiNH2 System".CHEMISTRY-AN ASIAN JOURNAL 5.7(2010):1594-1599.
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