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题名: Application of Organic Macrocyclic Supramolecular Structures on Adsorption and Conversion of Carbon Dioxide
作者: Li Peipei1;  Liu Li1
关键词: supramolecule ;  assembly ;  carbon dioxide ;  adsorption ;  conversion
刊名: PROGRESS IN CHEMISTRY
发表日期: 2010-10-01
卷: 22, 期:10, 页:1940-1951
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Adsorption and conversion of carbon dioxide has called worldwide attention not only due to the increasing environmental concerns, but also in view of the carbon resource utilization. The research progress on the physical adsorption and chemical conversion of carbon dioxide using organic macrocyclic supramolecular host structures, such as crown ether, cyclodextrin, calixarene and cucurbituril has been overviewed. With intrinsic cavity structure, the organic macrocyclic supramolecular hosts can further form porous materials through self-assembly. On one hand, selective adsorption and separation of carbon dioxide by the organic macrocyclic supramolecular hosts, their derivatives and porous self-assembly materials with specific size and versatile shapes are reviewed in this paper. On the other hand, the chemical conversion of carbon dioxide involves the reactions with amines, epoxides, alcohols and phenates in the presence of organic macrocyclic supramolecular host structures which act as reactants, catalysts or cocatalysts. These chemical transformations of carbon dioxide enable the utilization of carbon resource and the preparation of functional materials. The review demonstrates the unique applications of molecular recognition and assembly characteristics of organic macrocyclic supramolecular structures on the adsorption and conversion of carbon dioxide. The outlook of the research area is also provided.
关键词[WOS]: CROWN-ETHER ;  DIMETHYL CARBONATE ;  GAS-ADSORPTION ;  SOLID-STATE ;  REVERSIBLE CHEMISTRY ;  SELECTIVE ADSORPTION ;  CYCLIC CARBONATES ;  CRYSTAL-STRUCTURE ;  PROPYLENE-OXIDE ;  CO2 FIXATION
语种: 英语
WOS记录号: WOS:000283615400008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141856
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Li Peipei,Liu Li. Application of Organic Macrocyclic Supramolecular Structures on Adsorption and Conversion of Carbon Dioxide[J]. PROGRESS IN CHEMISTRY,2010,22(10):1940-1951.
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