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题名: Methylsulfonyl-Based Sulfamide-Amine Alcohol as a Ligand for Enantioselective Alkynylation of Aldehydes
作者: Jin Wei1;  Huang Yongbo1;  Wan Boshun1
关键词: sulfamide-amine alcohol ;  enantioselective addition ;  alkynylation ;  aldehyde
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2010-09-01
DOI: 10.1016/S1872-2067(10)60106-4
卷: 31, 期:9, 页:1098-1102
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: Chiral methylsulfonyl-based sulfamide-amine alcohol (SAA) ligands were synthesized from commercially available starting materials in two simple steps Methylsulfonyl-based SAA ligands catalyzed the asymmetric alkynylation of various aldehydes using alkynylzinc to provide chiral propargyl alcohols with moderate to good enantioselectivity up to 83% ee
关键词[WOS]: ASYMMETRIC ALKYNYLATION ;  AROMATIC KETONES ;  PHENYLACETYLENE ADDITION ;  TITANIUM COMPLEX ;  ALKYNE ADDITIONS ;  TERMINAL ALKYNES ;  CARBONYL GROUPS ;  ALKYNYLZINC ;  CATALYSIS ;  ACETYLENES
语种: 英语
WOS记录号: WOS:000282671300002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141911
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Jin Wei,Huang Yongbo,Wan Boshun. Methylsulfonyl-Based Sulfamide-Amine Alcohol as a Ligand for Enantioselective Alkynylation of Aldehydes[J]. CHINESE JOURNAL OF CATALYSIS,2010,31(9):1098-1102.
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