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题名: Chiral 1-phenylethylamine-derived phosphine-phosphoramidite ligands for highly enantioselective Rh-catalyzed hydrogenation of beta-(acylamino)acrylates: significant effect of substituents on 3,3 '-positions of binaphthyl moiety
作者: Zhou, Xiao-Mao2;  Huang, Jia-Di1;  Luo, Li-Bin2;  Zhang, Chen-Lu3;  Hu, Xiang-Ping1;  Zheng, Zhuo1
刊名: ORGANIC & BIOMOLECULAR CHEMISTRY
发表日期: 2010
DOI: 10.1039/c000268b
卷: 8, 期:10, 页:2320-2322
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A series of new chiral phosphine-phosphoramidite ligands with a 3,3'-substituted binaphthyl moiety were prepared from 1-phenylethylamine, and successfully applied in the Rh-catalyzed asymmetric hydrogenation of beta-(acylamino)acrylates. The research disclosed that the substituents on the 3,3'-positions of binaphthyl moiety significantly influenced the enantioselectivity.
关键词[WOS]: AMINO-ACID-DERIVATIVES ;  ASYMMETRIC HYDROGENATION ;  ROCHE ESTER ;  INDOLPHOS ;  HYDROFORMYLATION ;  COMPLEXES ;  QUINAPHOS
语种: 英语
WOS记录号: WOS:000277399300005
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141962
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Hunan Agr Univ, Inst Pesticide, Changsha 410128, Hunan, Peoples R China
3.Liaoning Normal Univ, Sch Chem & Chem Engn, Dalian 116029, Peoples R China

Recommended Citation:
Zhou, Xiao-Mao,Huang, Jia-Di,Luo, Li-Bin,et al. Chiral 1-phenylethylamine-derived phosphine-phosphoramidite ligands for highly enantioselective Rh-catalyzed hydrogenation of beta-(acylamino)acrylates: significant effect of substituents on 3,3 '-positions of binaphthyl moiety[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2010,8(10):2320-2322.
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