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题名: Two New Metal-Organic Frameworks with Mixed Ligands of Carboxylate and Bipyridine Synthesis, Crystal Structure, and Sensing for Methanol
作者: Song, Li-Fang1, 2;  Jiang, Chun-Hong1, 2;  Jiao, Cheng-Li1, 2;  Zhang, Jian1;  Sun, Li-Xian1;  Xu, Fen3;  You, Wan-Sheng3;  Wang, Zhong-Gang4;  Zhao, Ji-Jun5, 6
刊名: CRYSTAL GROWTH & DESIGN
发表日期: 2010-12-01
DOI: 10.1021/cg100599i
卷: 10, 期:12, 页:5020-5023
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Multidisciplinary ;  Crystallography ;  Materials Science, Multidisciplinary
研究领域[WOS]: Chemistry ;  Crystallography ;  Materials Science
英文摘要: Two new mixed ligand metal organic frameworks, [Cu-2(OH)(2,2' bipy)(2)(BTC) 2H(2)O](n) (1) and [Co(4 4' bipy) (m BDC)](n) (2) have been synthesized by hydrothermal reaction of Cu(COO)(2) H2O with 1 3 5 benzenetricarboxylic acid (H3BTC) and 2 2' bipyridine and of Co(NO3)(2) 6H(2)O with 1 3 benzenedicarboxylic acid (m H2BDC) and 4,4' bipyridine respectively They were characterized by single crystal X ray diffraction analysis powder XRD, elemental analysis TGA, and IR spectroscopy The adsorption characteristics of compounds 1 and 2 for methanol were investigated in situ with a quartz crystal microbalance (QCM) which indicated that they were highly sensitive to methanol at room temperature
关键词[WOS]: HYDROGEN STORAGE ;  COORDINATION POLYMERS ;  MOFS ;  SEPARATION ;  OXIDATION ;  CATALYSTS ;  CO2
语种: 英语
WOS记录号: WOS:000284675100002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141983
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
4.Dalian Univ Technol, Dept Polymer Sci & Mat, Sch Chem Engn, Dalian 116012, Peoples R China
5.Dalian Univ Technol, Sch Phys & Optoelect Technol, Dalian 116024, Peoples R China
6.Dalian Univ Technol, Coll Adv Sci & Technol, Dalian 116024, Peoples R China

Recommended Citation:
Song, Li-Fang,Jiang, Chun-Hong,Jiao, Cheng-Li,et al. Two New Metal-Organic Frameworks with Mixed Ligands of Carboxylate and Bipyridine Synthesis, Crystal Structure, and Sensing for Methanol[J]. CRYSTAL GROWTH & DESIGN,2010,10(12):5020-5023.
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