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题名: Reaction of alpha-Ene-Vinylcyclopropanes: Type II Intramolecular [5+2] Cycloaddition or [3+2] Cycloaddition?
作者: Li, Qian1;  Jiang, Guo-Jie1;  Jiao, Lei1;  Yu, Zhi-Xiang1
刊名: ORGANIC LETTERS
发表日期: 2010-03-19
DOI: 10.1021/ol100237h
卷: 12, 期:6, 页:1332-1335
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Exposure of alpha-ene-VCPs to catalytic [Rh(dppm)]SbF(6) led to the discovery of a novel Rh(I)-catalyzed [3+2] reaction, which was shown to be efficient for the construction of 5/6- and 5/7-bicyclic compounds rather than the anticipated type II [5+2] products.
关键词[WOS]: CATALYZED TRIMETHYLENEMETHANE CYCLOADDITIONS ;  ASYMMETRIC TOTAL-SYNTHESIS ;  (-)-PSEUDOLARIC ACID-B ;  7-MEMBERED RINGS ;  METAL ;  ALLENES ;  CYCLOISOMERIZATION ;  STEREOCHEMISTRY ;  REARRANGEMENTS ;  SELECTIVITY
语种: 英语
WOS记录号: WOS:000275379100048
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141991
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Coll Chem, Beijing 100871, Peoples R China

Recommended Citation:
Li, Qian,Jiang, Guo-Jie,Jiao, Lei,et al. Reaction of alpha-Ene-Vinylcyclopropanes: Type II Intramolecular [5+2] Cycloaddition or [3+2] Cycloaddition?[J]. ORGANIC LETTERS,2010,12(6):1332-1335.
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