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Reaction of alpha-Ene-Vinylcyclopropanes: Type II Intramolecular [5+2] Cycloaddition or [3+2] Cycloaddition?
Li, Qian; Jiang, Guo-Jie; Jiao, Lei; Yu, Zhi-Xiang
Source PublicationORGANIC LETTERS
2010-03-19
DOI10.1021/ol100237h
Volume12Issue:6Pages:1332-1335
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordCATALYZED TRIMETHYLENEMETHANE CYCLOADDITIONS ; ASYMMETRIC TOTAL-SYNTHESIS ; (-)-PSEUDOLARIC ACID-B ; 7-MEMBERED RINGS ; METAL ; ALLENES ; CYCLOISOMERIZATION ; STEREOCHEMISTRY ; REARRANGEMENTS ; SELECTIVITY
AbstractExposure of alpha-ene-VCPs to catalytic [Rh(dppm)]SbF(6) led to the discovery of a novel Rh(I)-catalyzed [3+2] reaction, which was shown to be efficient for the construction of 5/6- and 5/7-bicyclic compounds rather than the anticipated type II [5+2] products.
Language英语
WOS IDWOS:000275379100048
Citation statistics
Cited Times:53[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141991
Collection中国科学院大连化学物理研究所
AffiliationPeking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Coll Chem, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Li, Qian,Jiang, Guo-Jie,Jiao, Lei,et al. Reaction of alpha-Ene-Vinylcyclopropanes: Type II Intramolecular [5+2] Cycloaddition or [3+2] Cycloaddition?[J]. ORGANIC LETTERS,2010,12(6):1332-1335.
APA Li, Qian,Jiang, Guo-Jie,Jiao, Lei,&Yu, Zhi-Xiang.(2010).Reaction of alpha-Ene-Vinylcyclopropanes: Type II Intramolecular [5+2] Cycloaddition or [3+2] Cycloaddition?.ORGANIC LETTERS,12(6),1332-1335.
MLA Li, Qian,et al."Reaction of alpha-Ene-Vinylcyclopropanes: Type II Intramolecular [5+2] Cycloaddition or [3+2] Cycloaddition?".ORGANIC LETTERS 12.6(2010):1332-1335.
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