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题名: Vanadyl sulfate: A simple catalyst for oxidation of alcohols with molecular oxygen in combination with 2,2,6,6-tetramethyl-piperidyl-1-oxyl
作者: Du, Zhongtian1;  Ma, Jiping1, 2;  Ma, Hong1;  Wang, Min1, 2;  Huang, Yizheng1;  Xu, Jie1
关键词: Vanadyl sulfate ;  Catalytic oxidation ;  Oxygen ;  Alcohols ;  TEMPO
刊名: CATALYSIS COMMUNICATIONS
发表日期: 2010-03-31
DOI: 10.1016/j.catcom.2010.02.004
卷: 11, 期:8, 页:732-735
收录类别: SCI ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Inexpensive vanadyl sulfate was developed in combination with 2.2,6,6-tetramethyl-piperidyl-1-oxyl (TEMPO) for catalytic oxidation of alcohols with molecular oxygen. A wide range of alcohols were oxidized to the corresponding carbonyl compounds in good conversions under mild conditions. No ligands or extra bases were used. Acetonitrile was the suitable solvent to keep the high activity of this system. (C) 2010 Elsevier B.V. All rights reserved.
关键词[WOS]: SELECTIVE AEROBIC OXIDATION ;  BENZYLIC ALCOHOLS ;  HYDROGEN-PEROXIDE ;  MILD CONDITIONS ;  ALDEHYDES ;  COMPLEXES ;  TEMPO ;  KETONES ;  CHEMISTRY ;  NITRITE
语种: 英语
WOS记录号: WOS:000276785000012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141995
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China

Recommended Citation:
Du, Zhongtian,Ma, Jiping,Ma, Hong,et al. Vanadyl sulfate: A simple catalyst for oxidation of alcohols with molecular oxygen in combination with 2,2,6,6-tetramethyl-piperidyl-1-oxyl[J]. CATALYSIS COMMUNICATIONS,2010,11(8):732-735.
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