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题名: A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins
作者: Gao, Ying-Xiang2, 3;  Chang, Le2, 3;  Shi, Hang2, 3;  Liang, Bo2, 3;  Wongkhan, Kittiya1;  Chaiyaveij, Duangduan1;  Batsanov, Andrei S.1;  Marder, Todd B.1;  Li, Chuang-Chuang2, 3;  Yang, Zhen2, 3;  Huang, Yong2, 3
关键词: asymmetric catalysis ;  catalyst design ;  enantioselectivity ;  palladium, thiourea-oxazoline library
刊名: ADVANCED SYNTHESIS & CATALYSIS
发表日期: 2010-08-01
DOI: 10.1002/adsc.201000070
卷: 352, 期:11-12, 页:1955-1966
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Applied ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: We report herein the synthesis of novel chiral S,N-heterobidentate thiourea-oxazoline ligands and their application to palladium-catalyzed enantioselective bis(methoxycarbonylation)s of terminal olefins under mild conditions. Copper salts were found to play multiple roles in this reaction. Substituted 2-phenylsuccinates were obtained in >90% yield and up to 84% cc under optimized conditions.
关键词[WOS]: PAUSON-KHAND REACTION ;  ASYMMETRIC BIS(ALKOXYCARBONYLATION) REACTION ;  HYDRIDE TRANSFER REDUCTION ;  CROSS-COUPLING REACTIONS ;  BIS-ALKOXYCARBONYLATION ;  CARBON-MONOXIDE ;  SILVER-NITRATE ;  CARBONYLATIVE ANNULATION ;  SUPPORTED CATALYSTS ;  BIOXAZOLINE LIGAND
语种: 英语
WOS记录号: WOS:000281654500024
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142000
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Univ Durham, Dept Chem, Durham DH1 3LE, England
2.Peking Univ, Lab Chem Genom, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China
3.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, BNLMS,Coll Chem, Beijing 100871, Peoples R China

Recommended Citation:
Gao, Ying-Xiang,Chang, Le,Shi, Hang,et al. A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins[J]. ADVANCED SYNTHESIS & CATALYSIS,2010,352(11-12):1955-1966.
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