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A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins
Gao, Ying-Xiang2,3; Chang, Le2,3; Shi, Hang2,3; Liang, Bo2,3; Wongkhan, Kittiya1; Chaiyaveij, Duangduan1; Batsanov, Andrei S.1; Marder, Todd B.1; Li, Chuang-Chuang2,3; Yang, Zhen2,3; Huang, Yong2,3
KeywordAsymmetric Catalysis Catalyst Design Enantioselectivity Palladium Thiourea-oxazoline Library
Source PublicationADVANCED SYNTHESIS & CATALYSIS
2010-08-01
DOI10.1002/adsc.201000070
Volume352Issue:11-12Pages:1955-1966
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Applied ; Chemistry, Organic
WOS Research AreaChemistry
WOS KeywordPAUSON-KHAND REACTION ; ASYMMETRIC BIS(ALKOXYCARBONYLATION) REACTION ; HYDRIDE TRANSFER REDUCTION ; CROSS-COUPLING REACTIONS ; BIS-ALKOXYCARBONYLATION ; CARBON-MONOXIDE ; SILVER-NITRATE ; CARBONYLATIVE ANNULATION ; SUPPORTED CATALYSTS ; BIOXAZOLINE LIGAND
AbstractWe report herein the synthesis of novel chiral S,N-heterobidentate thiourea-oxazoline ligands and their application to palladium-catalyzed enantioselective bis(methoxycarbonylation)s of terminal olefins under mild conditions. Copper salts were found to play multiple roles in this reaction. Substituted 2-phenylsuccinates were obtained in >90% yield and up to 84% cc under optimized conditions.
Language英语
WOS IDWOS:000281654500024
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142000
Collection中国科学院大连化学物理研究所
Affiliation1.Univ Durham, Dept Chem, Durham DH1 3LE, England
2.Peking Univ, Lab Chem Genom, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China
3.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, BNLMS,Coll Chem, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Gao, Ying-Xiang,Chang, Le,Shi, Hang,et al. A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins[J]. ADVANCED SYNTHESIS & CATALYSIS,2010,352(11-12):1955-1966.
APA Gao, Ying-Xiang.,Chang, Le.,Shi, Hang.,Liang, Bo.,Wongkhan, Kittiya.,...&Huang, Yong.(2010).A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins.ADVANCED SYNTHESIS & CATALYSIS,352(11-12),1955-1966.
MLA Gao, Ying-Xiang,et al."A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins".ADVANCED SYNTHESIS & CATALYSIS 352.11-12(2010):1955-1966.
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