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Heat capacities and thermodynamic properties of a novel mixed-ligands MOFs
Song, Li-Fang1,2; Jiang, Chun-Hong1,2; Zhang, Jian1; Sun, Li-Xian1; Xu, Fen3; You, Wan-Sheng3; Zhao, Yi3; Zhang, Zhi-Heng4; Wang, Mei-Han5; Sawada, Yutake5; Cao, Zhong6; Zeng, Ju-Lan6
关键词Copper Metal-organic Frameworks Molar Heat Capacity Temperature Modulated Differential Scanning Calorimetry Thermogravimetry
刊名JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
2010-05-01
DOI10.1007/s10973-009-0207-0
100期:2页:679-684
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Analytical ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]METAL-ORGANIC FRAMEWORKS ; MODULATED DSC
英文摘要A novel metal-organic frameworks [Cu-2(OH)(2,2'-bpy)(2)(BTC) center dot A 2H(2)O](n) (CuMOF, BTC = benzene-1,3,5-tricarboxylic acid, 2,2'-bpy = 2,2'-bipyridine) has been synthesized hydrothermally and characterized by single crystal XRD, FT-IR spectra. The low-temperature molar heat capacities were measured by temperature modulated differential scanning calorimetry (TMDSC) for the first time. The thermodynamic parameters such as entropy and enthalpy relative to reference temperature 298.15 K were derived based on the above molar heat capacity data. Moreover, the thermal stability and the decomposition mechanism of CuMOF were investigated by TG-MS (thermogravimetry-mass spectrometer). A four-stage mass loss was observed in the TG curve. MS curve indicated that the gas products for oxidative degradation of CuMOF were H2O, CO2, NO and NO2.
语种英语
WOS记录号WOS:000276771600040
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被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142033
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
4.PetroChina Pipeline Co, Inst Appl Chem, R&D Ctr, Langfang 065000, Hebei, Peoples R China
5.Tokyo Polytech Univ, Fac Engn, Dept Nanochem, Kanagawa 2430297, Japan
6.Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410076, Hunan, Peoples R China
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Song, Li-Fang,Jiang, Chun-Hong,Zhang, Jian,et al. Heat capacities and thermodynamic properties of a novel mixed-ligands MOFs[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2010,100(2):679-684.
APA Song, Li-Fang.,Jiang, Chun-Hong.,Zhang, Jian.,Sun, Li-Xian.,Xu, Fen.,...&Zeng, Ju-Lan.(2010).Heat capacities and thermodynamic properties of a novel mixed-ligands MOFs.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,100(2),679-684.
MLA Song, Li-Fang,et al."Heat capacities and thermodynamic properties of a novel mixed-ligands MOFs".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 100.2(2010):679-684.
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