DICP OpenIR
A Lanthanide-Complex-Based Ratiometric Luminescent Probe Specific for Peroxynitrite
Song, Cuihong1; Ye, Zhiqiang2; Wang, Guilan2; Yuan, Jingli1,2; Guan, Yafeng1
KeywordAnalytical Methods Cell Imaging Lanthanides Luminescence Peroxynitrite
Source PublicationCHEMISTRY-A EUROPEAN JOURNAL
2010
DOI10.1002/chem.201000528
Volume16Issue:22Pages:6464-6472
Indexed BySCI ; IC
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordSINGLET OXYGEN ; EXCITED-STATES ; EUROPIUM ; INDICATORS ; OXIDATION ; CHELATE ; SENSOR ; CELLS
AbstractA lanthanide-complex-based ratiometric luminescence probe specific for peroxynitrite (ONOO-), 4'-(2,4-dimethoxyphenyl)-2,2':6',2 ''-terpyridine- 6,6 ''-diyl]bis(methylenenitrilo)tetrakis-(acetate)-Eu3+/Tb3+ ([Eu3+/Tb3+ (DTTA)]), has been designed and synthesized. Both [Eu3+(DTTA)] and [Tb3+(DTTA)] are highly water soluble with large stability constants at approximate to 10(20), and strongly luminescent with luminescence quantum yields of 10.0 and 9.9%, respectively, and long luminescence lifetimes of 1.38 and 0.26 ms, respectively. It was found that the luminescence of [Tb3+(DTTA)] could be quenched by ONOO- rapidly and specifically in aqueous buffers, while that of [Eu3+(DTTA)] did not respond to the addition of ONOO-. Thus, by simply mixing [Eu3+(DTTA)] and [Tb3+(DTTA)] in an aqueous buffer, a ratiometric luminescence probe specific for time-gated luminescence detection of ONOO- was obtained. The performance of [Tb3+(DTTA).] and [Eu3+/Tb3+(DTTA)] as the probes for luminescence imaging detection of ONOO- in living cells was investigated. The results demonstrated the efficacy and advantages of the new ratiometric luminescence probe for highly sensitive luminescence bioimaging application.
Language英语
WOS IDWOS:000279445400010
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142043
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dept Instrumentat & Analyt Sci, Dalian 116023, Peoples R China
2.Dalian Univ Technol, Sch Chem, Dalian 116012, Peoples R China
Recommended Citation
GB/T 7714
Song, Cuihong,Ye, Zhiqiang,Wang, Guilan,et al. A Lanthanide-Complex-Based Ratiometric Luminescent Probe Specific for Peroxynitrite[J]. CHEMISTRY-A EUROPEAN JOURNAL,2010,16(22):6464-6472.
APA Song, Cuihong,Ye, Zhiqiang,Wang, Guilan,Yuan, Jingli,&Guan, Yafeng.(2010).A Lanthanide-Complex-Based Ratiometric Luminescent Probe Specific for Peroxynitrite.CHEMISTRY-A EUROPEAN JOURNAL,16(22),6464-6472.
MLA Song, Cuihong,et al."A Lanthanide-Complex-Based Ratiometric Luminescent Probe Specific for Peroxynitrite".CHEMISTRY-A EUROPEAN JOURNAL 16.22(2010):6464-6472.
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