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A remarkable enhancement of catalytic activity for KBH4 treating the carbothermal reduced Ni/AC catalyst in glycerol hydrogenolysis
Yu, Weiqiang1,2; Xu, Jie1; Ma, Hong1; Chen, Chen1; Zhao, Jing1,2; Miao, Hong1; Song, Qi1,2
关键词Carbothermal Reduction Glycerol Hydrogenolysis Potassium Borohydride Propylene Glycol
刊名CATALYSIS COMMUNICATIONS
2010-01-25
DOI10.1016/j.catcom.2009.12.009
11期:5页:493-497
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]SUPPORTED NICKEL-CATALYSTS ; ION-EXCHANGE-RESIN ; PROPYLENE-GLYCOL ; ACTIVATED CARBON ; SELECTIVE HYDROGENOLYSIS ; PLATINUM CATALYSTS ; NI CATALYSTS ; HYDROGENATION ; RU
英文摘要It reported a novel procedure for preparing Ni/AC catalyst for the glycerol hydrogenolysis, which involved carbothermal reduction of supported nickel nitrate and further treatment with KBH4. The activity of the as-prepared catalyst was remarkably enhanced compared with KBH4, H-2 or carbothermal reduced Ni/AC catalyst. The Ni particles and the variation of oxygen-containing surface groups (OSGs) were studied by XRD, TEM, FT-IR, He-TPD and NH3-TPD techniques. The high dispersed Ni and the acidity generated by the OSGs have the synergy effect on the activity of glycerol hydrogenolysis. (C) 2009 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000274273300040
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被引频次:46[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142089
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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Yu, Weiqiang,Xu, Jie,Ma, Hong,et al. A remarkable enhancement of catalytic activity for KBH4 treating the carbothermal reduced Ni/AC catalyst in glycerol hydrogenolysis[J]. CATALYSIS COMMUNICATIONS,2010,11(5):493-497.
APA Yu, Weiqiang.,Xu, Jie.,Ma, Hong.,Chen, Chen.,Zhao, Jing.,...&Song, Qi.(2010).A remarkable enhancement of catalytic activity for KBH4 treating the carbothermal reduced Ni/AC catalyst in glycerol hydrogenolysis.CATALYSIS COMMUNICATIONS,11(5),493-497.
MLA Yu, Weiqiang,et al."A remarkable enhancement of catalytic activity for KBH4 treating the carbothermal reduced Ni/AC catalyst in glycerol hydrogenolysis".CATALYSIS COMMUNICATIONS 11.5(2010):493-497.
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