DICP OpenIR
A remarkable enhancement of catalytic activity for KBH4 treating the carbothermal reduced Ni/AC catalyst in glycerol hydrogenolysis
Yu, Weiqiang1,2; Xu, Jie1; Ma, Hong1; Chen, Chen1; Zhao, Jing1,2; Miao, Hong1; Song, Qi1,2
KeywordCarbothermal Reduction Glycerol Hydrogenolysis Potassium Borohydride Propylene Glycol
Source PublicationCATALYSIS COMMUNICATIONS
2010-01-25
DOI10.1016/j.catcom.2009.12.009
Volume11Issue:5Pages:493-497
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordSUPPORTED NICKEL-CATALYSTS ; ION-EXCHANGE-RESIN ; PROPYLENE-GLYCOL ; ACTIVATED CARBON ; SELECTIVE HYDROGENOLYSIS ; PLATINUM CATALYSTS ; NI CATALYSTS ; HYDROGENATION ; RU
AbstractIt reported a novel procedure for preparing Ni/AC catalyst for the glycerol hydrogenolysis, which involved carbothermal reduction of supported nickel nitrate and further treatment with KBH4. The activity of the as-prepared catalyst was remarkably enhanced compared with KBH4, H-2 or carbothermal reduced Ni/AC catalyst. The Ni particles and the variation of oxygen-containing surface groups (OSGs) were studied by XRD, TEM, FT-IR, He-TPD and NH3-TPD techniques. The high dispersed Ni and the acidity generated by the OSGs have the synergy effect on the activity of glycerol hydrogenolysis. (C) 2009 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000274273300040
Citation statistics
Cited Times:48[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142089
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Yu, Weiqiang,Xu, Jie,Ma, Hong,et al. A remarkable enhancement of catalytic activity for KBH4 treating the carbothermal reduced Ni/AC catalyst in glycerol hydrogenolysis[J]. CATALYSIS COMMUNICATIONS,2010,11(5):493-497.
APA Yu, Weiqiang.,Xu, Jie.,Ma, Hong.,Chen, Chen.,Zhao, Jing.,...&Song, Qi.(2010).A remarkable enhancement of catalytic activity for KBH4 treating the carbothermal reduced Ni/AC catalyst in glycerol hydrogenolysis.CATALYSIS COMMUNICATIONS,11(5),493-497.
MLA Yu, Weiqiang,et al."A remarkable enhancement of catalytic activity for KBH4 treating the carbothermal reduced Ni/AC catalyst in glycerol hydrogenolysis".CATALYSIS COMMUNICATIONS 11.5(2010):493-497.
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