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Solid Sulfonic Acid-Promoted Oxidation of Benzyl Alcohol Catalyzed by Isoamyl Nitrite
Sheng Xuebin1,2; Ma Hong1; Li Decai1; He Jing3; Xu Jie1
关键词Isoamyl Nitrite Nitrosonium Cation Solid Sulfonic Acid Benzyl Alcohol Oxidation Molecular Oxygen Benzyl Aldehyde
刊名CHINESE JOURNAL OF CATALYSIS
2010-07-01
DOI10.3724/SP.J.1088.2010.00109
31期:7页:822-826
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]NONLINEAR-OPTICAL APPLICATIONS ; TRANSITION-METAL-FREE ; MILD CONDITIONS ; HETEROGENEOUS SYSTEM ; SULFURIC ACID/NANO2 ; CARBONYL-COMPOUNDS ; AEROBIC OXIDATION ; SOLVENT-FREE ; OXYGEN ; DYE
英文摘要Isoamyl nitrite was employed to catalyze the selective oxidation of benzyl alcohol to benzyl aldehyde using molecular oxygen, in which solid sulfonic acid was used to promote the in situ generation of nitrosonium cation. Solid acid prepared by treating Amberlyst 15 at 300 degrees C demonstrated the best promotion effect, with which 90% conversion and 97% selectivity for benzyl aldehyde could be achieved at 80 degrees C under 0.5 MPa for 2 h. The differences of solid acids and their influence on oxidation were investigated by Fourier transform infrared spectroscopy, derivative thermogravimetry, and acid-base titration. Nitrosonium cation was detected by the derivative method using ultraviolet-visible absorption spectrometry.
语种英语
WOS记录号WOS:000280868900018
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被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142171
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.PetroChina Urumuqi Petrochem Co Fibre Mill, Urumqi 830019, Xinjiang, Peoples R China
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GB/T 7714
Sheng Xuebin,Ma Hong,Li Decai,et al. Solid Sulfonic Acid-Promoted Oxidation of Benzyl Alcohol Catalyzed by Isoamyl Nitrite[J]. CHINESE JOURNAL OF CATALYSIS,2010,31(7):822-826.
APA Sheng Xuebin,Ma Hong,Li Decai,He Jing,&Xu Jie.(2010).Solid Sulfonic Acid-Promoted Oxidation of Benzyl Alcohol Catalyzed by Isoamyl Nitrite.CHINESE JOURNAL OF CATALYSIS,31(7),822-826.
MLA Sheng Xuebin,et al."Solid Sulfonic Acid-Promoted Oxidation of Benzyl Alcohol Catalyzed by Isoamyl Nitrite".CHINESE JOURNAL OF CATALYSIS 31.7(2010):822-826.
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