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Ni/NaX: A Bifunctional Efficient Catalyst for Selective Hydrogenolysis of Glycerol
Zhao, Jing1,2; Yu, Weiqiang1,2; Chen, Chen1; Miao, Hong1; Ma, Hong1; Xu, Jie1
关键词Glycerol Hydrogenolysis Nickel Nax Zeolite Acidity
刊名CATALYSIS LETTERS
2010
DOI10.1007/s10562-009-0208-4
134期:1-2页:184-189
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]ION-EXCHANGE-RESIN ; BIOMASS ; 1,2-PROPANEDIOL ; RU/C
英文摘要Non-noble metal Ni/NaX catalyst was prepared and used in the hydrogenolysis of aqueous glycerol. Characterization by XRD, SAED, H(2) chemisorption, ICP and NH(3)-TPD techniques disclosed that the proper strong acid sites were responsible for the high activity and selectivity. Over Ni/NaX catalyst, conversion of glycerol reached 86.6% with 94.6% selectivity to glycols including 1,2-proplyene glycol and ethylene glycol under 6.0 MPa H(2) pressure at 200 A degrees C after 10 h reaction. Additionally, the effects of time, temperature, and H(2) pressure were investigated in detail.
语种英语
WOS记录号WOS:000274384600029
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142173
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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GB/T 7714
Zhao, Jing,Yu, Weiqiang,Chen, Chen,et al. Ni/NaX: A Bifunctional Efficient Catalyst for Selective Hydrogenolysis of Glycerol[J]. CATALYSIS LETTERS,2010,134(1-2):184-189.
APA Zhao, Jing,Yu, Weiqiang,Chen, Chen,Miao, Hong,Ma, Hong,&Xu, Jie.(2010).Ni/NaX: A Bifunctional Efficient Catalyst for Selective Hydrogenolysis of Glycerol.CATALYSIS LETTERS,134(1-2),184-189.
MLA Zhao, Jing,et al."Ni/NaX: A Bifunctional Efficient Catalyst for Selective Hydrogenolysis of Glycerol".CATALYSIS LETTERS 134.1-2(2010):184-189.
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