中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Synthesis, Crystal Structure, and Characterization of a New Metal Borophosphate: Pb-4(II){Co-2[B(OH)(2)P2O8](PO4)(2)}Cl
作者: Yang, Miao1, 2;  Chen, Peng3, 4;  Welz-Biermann, Urs1
关键词: Hydrothermal synthesis ;  Crystal growth ;  Xray diffraction ;  Boron ;  Lead
刊名: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
发表日期: 2010
DOI: 10.1002/zaac.201000166
卷: 636, 期:8, 页:1454-1460
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear
研究领域[WOS]: Chemistry
英文摘要: A new metal borophosphate Pb-4(II){Co-2[B(OH)(2)P2O8](PO4)(2)}Cl (1), containing both Pb2+ cations and Cl- anions, was hydrothemially synthesized and characterized by powder X-ray diffraction, ICP, TG/DTA, and FTIR spectroscopic analyses. The crystal structure determination from single-crystal X-ray diffraction reveals that compound 1 crystallizes in the trigonal space group R (3) over barc (No. 167), a = 9.7513(7) angstrom, c = 91.060(13) angstrom, V = 7498.7(13) angstrom(3) and Z = 18. Its structure features a new cobalt borophosphate layer {Co-2[B(OH)(2)P2O8](PO4)(2)}(7-) built up from CoO5 square pyramids, [B(OH)(2)P2O8](5-) borophosphate timers and PO4 tetrahedra. Extraframework Pb2+ and Cl- ions are located at the vacancy of layers to achieve the charge neutrality of the framework. Magnetic measurements indicate that antiferromagnetic interactions exist between Co2+ ions with a negative Weiss constant of -20.3 K.
关键词[WOS]: MONOPHOSPHATE-HYDROGENMONOBORATE-MONOPHOSPHATE ;  LEAD BOROPHOSPHATE ;  FRAMEWORK
语种: 英语
WOS记录号: WOS:000280659500007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142191
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Chinal Ion Liquid Lab, Dalian 116023, Peoples R China
2.Max Planck Inst Chem Phys Fester Stoffe, D-01187 Dresden, Germany
3.Heilongjiang Univ, Key Lab Heilongjiang Prov, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
4.Heilongjiang Univ, Educ Dept Heilongjiang Prov, Sch Chem & Mat Sci, Harbin 150080, Peoples R China

Recommended Citation:
Yang, Miao,Chen, Peng,Welz-Biermann, Urs. Synthesis, Crystal Structure, and Characterization of a New Metal Borophosphate: Pb-4(II){Co-2[B(OH)(2)P2O8](PO4)(2)}Cl[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2010,636(8):1454-1460.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Yang, Miao]'s Articles
 [Chen, Peng]'s Articles
 [Welz-Biermann, Urs]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Yang, Miao]‘s Articles
 [Chen, Peng]‘s Articles
 [Welz-Biermann, Urs]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace