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Synthesis, Crystal Structure, and Characterization of a New Metal Borophosphate: Pb-4(II){Co-2[B(OH)(2)P2O8](PO4)(2)}Cl
Yang, Miao1,2; Chen, Peng3,4; Welz-Biermann, Urs1
关键词Hydrothermal Synthesis Crystal Growth Xray Diffraction Boron Lead
刊名ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
2010
DOI10.1002/zaac.201000166
636期:8页:1454-1460
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear
研究领域[WOS]Chemistry
关键词[WOS]MONOPHOSPHATE-HYDROGENMONOBORATE-MONOPHOSPHATE ; LEAD BOROPHOSPHATE ; FRAMEWORK
英文摘要A new metal borophosphate Pb-4(II){Co-2[B(OH)(2)P2O8](PO4)(2)}Cl (1), containing both Pb2+ cations and Cl- anions, was hydrothemially synthesized and characterized by powder X-ray diffraction, ICP, TG/DTA, and FTIR spectroscopic analyses. The crystal structure determination from single-crystal X-ray diffraction reveals that compound 1 crystallizes in the trigonal space group R (3) over barc (No. 167), a = 9.7513(7) angstrom, c = 91.060(13) angstrom, V = 7498.7(13) angstrom(3) and Z = 18. Its structure features a new cobalt borophosphate layer {Co-2[B(OH)(2)P2O8](PO4)(2)}(7-) built up from CoO5 square pyramids, [B(OH)(2)P2O8](5-) borophosphate timers and PO4 tetrahedra. Extraframework Pb2+ and Cl- ions are located at the vacancy of layers to achieve the charge neutrality of the framework. Magnetic measurements indicate that antiferromagnetic interactions exist between Co2+ ions with a negative Weiss constant of -20.3 K.
语种英语
WOS记录号WOS:000280659500007
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被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142191
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Chinal Ion Liquid Lab, Dalian 116023, Peoples R China
2.Max Planck Inst Chem Phys Fester Stoffe, D-01187 Dresden, Germany
3.Heilongjiang Univ, Key Lab Heilongjiang Prov, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
4.Heilongjiang Univ, Educ Dept Heilongjiang Prov, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
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Yang, Miao,Chen, Peng,Welz-Biermann, Urs. Synthesis, Crystal Structure, and Characterization of a New Metal Borophosphate: Pb-4(II){Co-2[B(OH)(2)P2O8](PO4)(2)}Cl[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2010,636(8):1454-1460.
APA Yang, Miao,Chen, Peng,&Welz-Biermann, Urs.(2010).Synthesis, Crystal Structure, and Characterization of a New Metal Borophosphate: Pb-4(II){Co-2[B(OH)(2)P2O8](PO4)(2)}Cl.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,636(8),1454-1460.
MLA Yang, Miao,et al."Synthesis, Crystal Structure, and Characterization of a New Metal Borophosphate: Pb-4(II){Co-2[B(OH)(2)P2O8](PO4)(2)}Cl".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 636.8(2010):1454-1460.
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