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题名: Product rotational Franck-Condon oscillations in HOD (Jka,kc) dissociation
作者: Cheng, Lina2;  Yuan, Kaijun2;  Cheng, Yuan2;  Guo, Qing2;  Yang, Xueming2;  Dixon, Richard N.1
关键词: photodissociation ;  HOD ;  Franck-Condon ;  Oscillations
刊名: MOLECULAR PHYSICS
发表日期: 2010
DOI: 10.1080/00268970903563469
卷: 108, 期:7-9, 页:905-914
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Physics
英文摘要: The technique of H(D) atom photofragment translation spectroscopy has been used to investigate the dissociation of jet-cooled HOD molecules following excitation to individual rovibrational levels of its (C) over tilde((1)B(1)) Rydberg state near 124 nm. Spectra have been recorded for both the D + OH and H + OD dissociation channels. The branching ratios between OH/OD(X (2)Pi, high nu, low N), OH/OD(X (2)Pi, low nu, high N), and OH/OD(A (2)Sigma(+)) channels vary between different parent rotational levels, and between the OH and OD products. The variation between the OH and OD channels can be attributed to an isotopic mass effect on the rotational axes which influences non-adiabatic coupling strengths. In addition, there is a population alternation with product rotational quantum number N for the OH/OD(X, high nu, low N) product, most striking for the OH case, the sense of which is correlated with the value of the parent pseudo-quantum number K(a)(1). It is shown that this is a consequence of recoil forces which lead to a closing of the HOD angle to near 90 degrees accompanying non-adiabatic transfer from the (C) over tilde state to the (A) over tilde((1)B(1)) state. The oscillation in population then derives from the symmetry properties around this angle of the product rotational wavefunctions. This suggests that the symmetry-induced population oscillation can only occur for a narrowly defined angular dissociation path. Model calculations also explain the different structure of the spin-orbit doubled low N band heads for each nu(OH/OD) which also alternates for even and odd K(a)(1). The necessary conditions to observe these phenomena are discussed.
关键词[WOS]: STATE DYNAMICAL PICTURE ;  ABSORPTION-BAND ;  LAMBDA-DOUBLET ;  121.6 NM ;  PHOTODISSOCIATION ;  H2O ;  OH ;  PHOTOFRAGMENTATION ;  DISTRIBUTIONS ;  PATHWAYS
语种: 英语
WOS记录号: WOS:000278110600009
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142192
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Cheng, Lina,Yuan, Kaijun,Cheng, Yuan,et al. Product rotational Franck-Condon oscillations in HOD (Jka,kc) dissociation[J]. MOLECULAR PHYSICS,2010,108(7-9):905-914.
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