中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Aerobic oxidative desulfurization of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene using an Anderson-type catalyst [(C18H37)(2)N(CH3)(2)](5)[IMo6O24]
作者: Lue, Hongying1;  Zhang, Yongna2;  Jiang, Zongxuan2;  Li, Can2
刊名: GREEN CHEMISTRY
发表日期: 2010
DOI: 10.1039/c0gc00271b
卷: 12, 期:11, 页:1954-1958
收录类别: SCI ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Benzothiophene (BT), dibenzothiophene (DBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT) are oxidized to their corresponding sulfones by an Anderson-type catalyst [(C18H37)(2)N(CH3)(2)](5)IMo6O24 using molecular oxygen as the oxidant under mild reaction conditions. These refractory sulfur-containing compounds can be oxidized completely in the absence of any sacrificial agent. Solvents such as acetonitrile and water play a negative effect on the oxidative desulfurization system. The catalytic activities of the amphiphilic Anderson catalysts depend on the quaternary ammonium cations. The reactivity of the sulfur-containing compounds follows the order 4,6-DMDBT > DBT > BT.
关键词[WOS]: ULTRA-DEEP DESULFURIZATION ;  SELECTIVE OXIDATION ;  MOLECULAR-OXYGEN ;  CHEMICAL OXIDATION ;  EMULSION DROPLETS ;  HYDROGEN-PEROXIDE ;  DIESEL FUEL ;  ACID ;  HEXAMOLYBDOCHROMATE(III) ;  EXTRACTION
语种: 英语
WOS记录号: WOS:000283936800012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142195
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Yantai Univ, Sci & Engn Coll Chem & Biol, Yantai 264005, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Lue, Hongying,Zhang, Yongna,Jiang, Zongxuan,et al. Aerobic oxidative desulfurization of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene using an Anderson-type catalyst [(C18H37)(2)N(CH3)(2)](5)[IMo6O24][J]. GREEN CHEMISTRY,2010,12(11):1954-1958.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Lue, Hongying]'s Articles
 [Zhang, Yongna]'s Articles
 [Jiang, Zongxuan]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Lue, Hongying]‘s Articles
 [Zhang, Yongna]‘s Articles
 [Jiang, Zongxuan]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace