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题名: Synthesis, crystal structure and photoelectric property of two new coordination polymers constructed by longer-spanning suberic acid and 4,4 '-bipyridine ligands
作者: Xie, Yan1, 4;  Bai, Feng Ying1;  Li, Jing1;  Xing, Yong Heng1;  Wang, Zhuo1;  Zhao, Hai Yan1;  Pu, Zhi Feng2;  Ge, Mao Fa2;  Shi, Zhan3
关键词: Coordination polymer ;  Suberic acid ;  Synthesis ;  Crystal structure ;  Surface photovoltage spectrum
刊名: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
发表日期: 2010-11-01
DOI: 10.1016/j.saa.2010.07.009
卷: 77, 期:4, 页:749-754
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Technology
类目[WOS]: Spectroscopy
研究领域[WOS]: Spectroscopy
英文摘要: Two-dimensional coordination polymers, [M(C8H12O4)(C10H8N2)]center dot H2O [M = Co (1), Cd (2); C10H8N2 = 4,4-bipyridine, C8H14O4 = subaric acid] were obtained from the reaction of the metal salts, bipy and subaric acid at 180 C and characterized by elemental analysis, infrared spectrum, and single-crystal X-ray diffraction and surface photovoltage spectrum (SPS). The single-crystal X-ray diffraction showed that the subaric ligand in the two complexes exhibits two types of modes coordinating to transition metal ions, resulting in the formation of a 1D infinite chain along the c-axis. In addition, the results of SPS for complexes 1 and 2 indicate that these two complexes exhibit positive surface photovoltage responses in the range of 300-800 nm, which can be assigned to LMCT and MLCT, respectively. And the SPS of complex 1 also can be assigned to the d -> d* electronic transition. The SPS spectra of the two complexes are consistent with their UV-vis spectra. (C) 2010 Elsevier B.V. All rights reserved.
关键词[WOS]: HYDROTHERMAL SYNTHESIS ;  MAGNETIC-PROPERTIES ;  LUMINESCENT PROPERTIES ;  FRAMEWORK ;  COMPLEXES ;  DICARBOXYLATE ;  NETWORKS ;  CO ;  CARBOXYLATE ;  POROSITY
语种: 英语
WOS记录号: WOS:000283906100006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142200
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
3.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Xie, Yan,Bai, Feng Ying,Li, Jing,et al. Synthesis, crystal structure and photoelectric property of two new coordination polymers constructed by longer-spanning suberic acid and 4,4 '-bipyridine ligands[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2010,77(4):749-754.
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