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题名: Synthesis, structure and dehydrogenation of magnesium amidoborane monoammoniate
作者: Chua, Yong Shen2;  Wu, Guotao1;  Xiong, Zhitao1;  Karkamkar, Abhi3;  Guo, Jianping1;  Jian, Mingxian2;  Wong, Ming Wah2;  Autrey, Thomas3;  Chen, Ping1
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2010
DOI: 10.1039/c0cc01260b
卷: 46, 期:31, 页:5752-5754
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Magnesium amidoborane monoammoniate (Mg(NH(2)BH(3))(2)center dot NH(3)) which crystallizes in a monoclinic structure (space group P2(1)/a) has been synthesized by reacting MgNH with NH(3)BH(3). Dihydrogen bonds are established between coordinated NH(3) and BH(3) of [NH(2)BH(3)](-) in the structure, promoting stoichiometric conversion of NH(3) to H(2).
关键词[WOS]: HYDROGEN STORAGE MATERIAL ;  LITHIUM BOROHYDRIDE ;  AMMONIA-BORANE ;  SYSTEM
语种: 英语
WOS记录号: WOS:000280514500036
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142208
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Natl Univ Singapore, Dept Chem, Singapore 117542, Singapore
3.Pacific NW Natl Lab, Richland, WA 99352 USA

Recommended Citation:
Chua, Yong Shen,Wu, Guotao,Xiong, Zhitao,et al. Synthesis, structure and dehydrogenation of magnesium amidoborane monoammoniate[J]. CHEMICAL COMMUNICATIONS,2010,46(31):5752-5754.
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