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题名: Rh(III)-Catalyzed Oxidative Coupling of N-Aryl-2-aminopyridine with Alkynes and Alkenes
作者: Chen, Jinlei2;  Song, Guoyong1;  Pan, Cheng-Ling1;  Li, Xingwei1
刊名: ORGANIC LETTERS
发表日期: 2010-12-03
DOI: 10.1021/ol1022596
卷: 12, 期:23, 页:5426-5429
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: [RhCp*Cl-2](2) (1-2 mol %) can catalyze the oxidative coupling of N-aryl-2-aminopyridines with alkynes and arylates to give N-(2-pyridyl)indoles and N-(2-pyridyl)quinolones, respectively, using Cu(OAc)(2) as an oxidant. Coupling with styrenes gave mono- and/or disubstituted olefination products.
关键词[WOS]: C-H BOND ;  INTERNAL ALKYNES ;  ORGANIC-SYNTHESIS ;  ROOM-TEMPERATURE ;  BENZOIC-ACIDS ;  ACTIVATION ;  CLEAVAGE ;  FUNCTIONALIZATION ;  RH ;  COUPLING/CYCLIZATION
语种: 英语
WOS记录号: WOS:000284555600018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142209
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Jilin Univ, State Key Lab Theoret & Computat Chem, Changchun 130023, Peoples R China

Recommended Citation:
Chen, Jinlei,Song, Guoyong,Pan, Cheng-Ling,et al. Rh(III)-Catalyzed Oxidative Coupling of N-Aryl-2-aminopyridine with Alkynes and Alkenes[J]. ORGANIC LETTERS,2010,12(23):5426-5429.
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