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CATALYTIC POLYMERIC HOLLOW-FIBER REACTORS FOR THE SELECTIVE HYDROGENATION OF CONJUGATED DIENES
GAO, HR; XU, Y; LIAO, SJ; LIU, R; LIU, J; LI, DC; YU, DR; ZHAO, YK; FAN, YH
关键词Polymeric Hollow Fibers Membrane Reactors Selective Hydrogenation Conjugated Dienes Polymer Anchored Palladium Complexes
刊名JOURNAL OF MEMBRANE SCIENCE
1995-10-31
106期:3页:213-219
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Technology ; Physical Sciences
类目[WOS]Engineering, Chemical ; Polymer Science
研究领域[WOS]Engineering ; Polymer Science
关键词[WOS]MEMBRANE REACTOR ; ACID CATALYST
英文摘要The catalytic polymeric hollow fibers, PVP-Pd/CA, PVP-Pd/PSF, PVP-Pd/PAN, EC-Pd/CA and AR-Pd/CA (PVP = polyvinylpyrrolidone, EC = ethyl cellulose, AR = melamine-formaidehyde resin, CA = cellulose acetate, PSF = polysulfone, PAN = polyacrylonitrile), were prepared by supporting the soluble polymer anchored palladium complexes of PVP-Pd, EC-Pd and AR-Pd on the corresponding CA, PSF and PAN hollow fibers, respectively. These catalytic polymeric hollow fibers were used to establish the catalytic membrane reactors, and the selective hydrogenation of conjugated dienes was carried out in reactors under mild conditions of 40 degrees C and 0.1 MPa. All of the catalytic hollow fibers are active and stable for the hydrogenation of conjugated dienes. The selectivity for the formation of monoene and the conversion of diene can simultaneously be up to more than 91% in the membrane reactors established with the PVP-Pd/CA and PVP-Pd/PAN catalytic hollow fibers.
语种英语
WOS记录号WOS:A1995TE20800003
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142218
专题中国科学院大连化学物理研究所
作者单位1.CHINESE ACAD SCI, DALIAN INST CHEM PHYS, DALIAN 116023, PEOPLES R CHINA
2.LIAONING NORMAL UNIV, DEPT CHEM, DALIAN 116021, PEOPLES R CHINA
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GB/T 7714
GAO, HR,XU, Y,LIAO, SJ,et al. CATALYTIC POLYMERIC HOLLOW-FIBER REACTORS FOR THE SELECTIVE HYDROGENATION OF CONJUGATED DIENES[J]. JOURNAL OF MEMBRANE SCIENCE,1995,106(3):213-219.
APA GAO, HR.,XU, Y.,LIAO, SJ.,LIU, R.,LIU, J.,...&FAN, YH.(1995).CATALYTIC POLYMERIC HOLLOW-FIBER REACTORS FOR THE SELECTIVE HYDROGENATION OF CONJUGATED DIENES.JOURNAL OF MEMBRANE SCIENCE,106(3),213-219.
MLA GAO, HR,et al."CATALYTIC POLYMERIC HOLLOW-FIBER REACTORS FOR THE SELECTIVE HYDROGENATION OF CONJUGATED DIENES".JOURNAL OF MEMBRANE SCIENCE 106.3(1995):213-219.
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