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题名: CATALYTIC POLYMERIC HOLLOW-FIBER REACTORS FOR THE SELECTIVE HYDROGENATION OF CONJUGATED DIENES
作者: GAO, HR;  XU, Y;  LIAO, SJ;  LIU, R;  LIU, J;  LI, DC;  YU, DR;  ZHAO, YK;  FAN, YH
关键词: POLYMERIC HOLLOW FIBERS ;  MEMBRANE REACTORS ;  SELECTIVE HYDROGENATION ;  CONJUGATED DIENES ;  POLYMER ANCHORED PALLADIUM COMPLEXES
刊名: JOURNAL OF MEMBRANE SCIENCE
发表日期: 1995-10-31
卷: 106, 期:3, 页:213-219
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Technology ;  Physical Sciences
类目[WOS]: Engineering, Chemical ;  Polymer Science
研究领域[WOS]: Engineering ;  Polymer Science
英文摘要: The catalytic polymeric hollow fibers, PVP-Pd/CA, PVP-Pd/PSF, PVP-Pd/PAN, EC-Pd/CA and AR-Pd/CA (PVP = polyvinylpyrrolidone, EC = ethyl cellulose, AR = melamine-formaidehyde resin, CA = cellulose acetate, PSF = polysulfone, PAN = polyacrylonitrile), were prepared by supporting the soluble polymer anchored palladium complexes of PVP-Pd, EC-Pd and AR-Pd on the corresponding CA, PSF and PAN hollow fibers, respectively. These catalytic polymeric hollow fibers were used to establish the catalytic membrane reactors, and the selective hydrogenation of conjugated dienes was carried out in reactors under mild conditions of 40 degrees C and 0.1 MPa. All of the catalytic hollow fibers are active and stable for the hydrogenation of conjugated dienes. The selectivity for the formation of monoene and the conversion of diene can simultaneously be up to more than 91% in the membrane reactors established with the PVP-Pd/CA and PVP-Pd/PAN catalytic hollow fibers.
关键词[WOS]: MEMBRANE REACTOR ;  ACID CATALYST
语种: 英语
WOS记录号: WOS:A1995TE20800003
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142218
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.CHINESE ACAD SCI, DALIAN INST CHEM PHYS, DALIAN 116023, PEOPLES R CHINA
2.LIAONING NORMAL UNIV, DEPT CHEM, DALIAN 116021, PEOPLES R CHINA

Recommended Citation:
GAO, HR,XU, Y,LIAO, SJ,et al. CATALYTIC POLYMERIC HOLLOW-FIBER REACTORS FOR THE SELECTIVE HYDROGENATION OF CONJUGATED DIENES[J]. JOURNAL OF MEMBRANE SCIENCE,1995,106(3):213-219.
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