DICP OpenIR
CATALYTIC POLYMERIC HOLLOW-FIBER REACTORS FOR THE SELECTIVE HYDROGENATION OF CONJUGATED DIENES
GAO, HR; XU, Y; LIAO, SJ; LIU, R; LIU, J; LI, DC; YU, DR; ZHAO, YK; FAN, YH
KeywordPolymeric Hollow Fibers Membrane Reactors Selective Hydrogenation Conjugated Dienes Polymer Anchored Palladium Complexes
Source PublicationJOURNAL OF MEMBRANE SCIENCE
1995-10-31
Volume106Issue:3Pages:213-219
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Technology ; Physical Sciences
WOS SubjectEngineering, Chemical ; Polymer Science
WOS Research AreaEngineering ; Polymer Science
WOS KeywordMEMBRANE REACTOR ; ACID CATALYST
AbstractThe catalytic polymeric hollow fibers, PVP-Pd/CA, PVP-Pd/PSF, PVP-Pd/PAN, EC-Pd/CA and AR-Pd/CA (PVP = polyvinylpyrrolidone, EC = ethyl cellulose, AR = melamine-formaidehyde resin, CA = cellulose acetate, PSF = polysulfone, PAN = polyacrylonitrile), were prepared by supporting the soluble polymer anchored palladium complexes of PVP-Pd, EC-Pd and AR-Pd on the corresponding CA, PSF and PAN hollow fibers, respectively. These catalytic polymeric hollow fibers were used to establish the catalytic membrane reactors, and the selective hydrogenation of conjugated dienes was carried out in reactors under mild conditions of 40 degrees C and 0.1 MPa. All of the catalytic hollow fibers are active and stable for the hydrogenation of conjugated dienes. The selectivity for the formation of monoene and the conversion of diene can simultaneously be up to more than 91% in the membrane reactors established with the PVP-Pd/CA and PVP-Pd/PAN catalytic hollow fibers.
Language英语
WOS IDWOS:A1995TE20800003
Citation statistics
Cited Times:40[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142218
Collection中国科学院大连化学物理研究所
Affiliation1.CHINESE ACAD SCI, DALIAN INST CHEM PHYS, DALIAN 116023, PEOPLES R CHINA
2.LIAONING NORMAL UNIV, DEPT CHEM, DALIAN 116021, PEOPLES R CHINA
Recommended Citation
GB/T 7714
GAO, HR,XU, Y,LIAO, SJ,et al. CATALYTIC POLYMERIC HOLLOW-FIBER REACTORS FOR THE SELECTIVE HYDROGENATION OF CONJUGATED DIENES[J]. JOURNAL OF MEMBRANE SCIENCE,1995,106(3):213-219.
APA GAO, HR.,XU, Y.,LIAO, SJ.,LIU, R.,LIU, J.,...&FAN, YH.(1995).CATALYTIC POLYMERIC HOLLOW-FIBER REACTORS FOR THE SELECTIVE HYDROGENATION OF CONJUGATED DIENES.JOURNAL OF MEMBRANE SCIENCE,106(3),213-219.
MLA GAO, HR,et al."CATALYTIC POLYMERIC HOLLOW-FIBER REACTORS FOR THE SELECTIVE HYDROGENATION OF CONJUGATED DIENES".JOURNAL OF MEMBRANE SCIENCE 106.3(1995):213-219.
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