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Vibrational state distributions following the photodissociation of CF3I near 304 nm
Yu, Zijun; Cheng, Min; Xu, Xiling; Yu, Dan; Du, Yikui; Zhu, Qihe
Source PublicationCHEMICAL PHYSICS LETTERS
2010-03-22
DOI10.1016/j.cplett.2010.02.044
Volume488Issue:4-6Pages:158-161
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Physics
WOS KeywordPHOTOFRAGMENT TRANSLATIONAL SPECTROSCOPY ; RECOIL ANISOTROPY ; ENERGY DEPENDENCE ; MOLECULES ; DISSOCIATION ; DYNAMICS ; SPECTRA ; IODIDE ; CH3I
AbstractThe photodissociation of CF3I has been studied near 304 nm. The partially resolved vibrational peaks in the I* and I channels reveal that the nu(2) umbrella mode of CF3 is preferentially excited. Besides, in the I* channel, the extra vibrational peaks assigned to the umbrella mode of CF3 from the hot band nu(3)' 1, 2 states of CF3I are also partially resolved. The E-int/E-avl shows a gradual increase as the state of CF3I changes from nu(3)' = 0 to nu(3)' = 2. The anisotropy parameter is also obtained and discussed with the interrelation of the (3)Q(1), (3)Q(0), and (1)Q(1) potential energy surfaces. (C) 2010 Elsevier B. V. All rights reserved.
Language英语
WOS IDWOS:000275751900011
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142240
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Natl Lab Mol Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Yu, Zijun,Cheng, Min,Xu, Xiling,et al. Vibrational state distributions following the photodissociation of CF3I near 304 nm[J]. CHEMICAL PHYSICS LETTERS,2010,488(4-6):158-161.
APA Yu, Zijun,Cheng, Min,Xu, Xiling,Yu, Dan,Du, Yikui,&Zhu, Qihe.(2010).Vibrational state distributions following the photodissociation of CF3I near 304 nm.CHEMICAL PHYSICS LETTERS,488(4-6),158-161.
MLA Yu, Zijun,et al."Vibrational state distributions following the photodissociation of CF3I near 304 nm".CHEMICAL PHYSICS LETTERS 488.4-6(2010):158-161.
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