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Vibrational state distributions following the photodissociation of CF3I near 304 nm
Yu, Zijun; Cheng, Min; Xu, Xiling; Yu, Dan; Du, Yikui; Zhu, Qihe
刊名CHEMICAL PHYSICS LETTERS
2010-03-22
DOI10.1016/j.cplett.2010.02.044
488期:4-6页:158-161
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]PHOTOFRAGMENT TRANSLATIONAL SPECTROSCOPY ; RECOIL ANISOTROPY ; ENERGY DEPENDENCE ; MOLECULES ; DISSOCIATION ; DYNAMICS ; SPECTRA ; IODIDE ; CH3I
英文摘要The photodissociation of CF3I has been studied near 304 nm. The partially resolved vibrational peaks in the I* and I channels reveal that the nu(2) umbrella mode of CF3 is preferentially excited. Besides, in the I* channel, the extra vibrational peaks assigned to the umbrella mode of CF3 from the hot band nu(3)' 1, 2 states of CF3I are also partially resolved. The E-int/E-avl shows a gradual increase as the state of CF3I changes from nu(3)' = 0 to nu(3)' = 2. The anisotropy parameter is also obtained and discussed with the interrelation of the (3)Q(1), (3)Q(0), and (1)Q(1) potential energy surfaces. (C) 2010 Elsevier B. V. All rights reserved.
语种英语
WOS记录号WOS:000275751900011
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142240
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Natl Lab Mol Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China
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Yu, Zijun,Cheng, Min,Xu, Xiling,et al. Vibrational state distributions following the photodissociation of CF3I near 304 nm[J]. CHEMICAL PHYSICS LETTERS,2010,488(4-6):158-161.
APA Yu, Zijun,Cheng, Min,Xu, Xiling,Yu, Dan,Du, Yikui,&Zhu, Qihe.(2010).Vibrational state distributions following the photodissociation of CF3I near 304 nm.CHEMICAL PHYSICS LETTERS,488(4-6),158-161.
MLA Yu, Zijun,et al."Vibrational state distributions following the photodissociation of CF3I near 304 nm".CHEMICAL PHYSICS LETTERS 488.4-6(2010):158-161.
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