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题名: Vibrational state distributions following the photodissociation of CF3I near 304 nm
作者: Yu, Zijun1;  Cheng, Min1;  Xu, Xiling1;  Yu, Dan1;  Du, Yikui1;  Zhu, Qihe1
刊名: CHEMICAL PHYSICS LETTERS
发表日期: 2010-03-22
DOI: 10.1016/j.cplett.2010.02.044
卷: 488, 期:4-6, 页:158-161
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Chemistry ;  Physics
英文摘要: The photodissociation of CF3I has been studied near 304 nm. The partially resolved vibrational peaks in the I* and I channels reveal that the nu(2) umbrella mode of CF3 is preferentially excited. Besides, in the I* channel, the extra vibrational peaks assigned to the umbrella mode of CF3 from the hot band nu(3)' 1, 2 states of CF3I are also partially resolved. The E-int/E-avl shows a gradual increase as the state of CF3I changes from nu(3)' = 0 to nu(3)' = 2. The anisotropy parameter is also obtained and discussed with the interrelation of the (3)Q(1), (3)Q(0), and (1)Q(1) potential energy surfaces. (C) 2010 Elsevier B. V. All rights reserved.
关键词[WOS]: PHOTOFRAGMENT TRANSLATIONAL SPECTROSCOPY ;  RECOIL ANISOTROPY ;  ENERGY DEPENDENCE ;  MOLECULES ;  DISSOCIATION ;  DYNAMICS ;  SPECTRA ;  IODIDE ;  CH3I
语种: 英语
WOS记录号: WOS:000275751900011
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142240
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Natl Lab Mol Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China

Recommended Citation:
Yu, Zijun,Cheng, Min,Xu, Xiling,et al. Vibrational state distributions following the photodissociation of CF3I near 304 nm[J]. CHEMICAL PHYSICS LETTERS,2010,488(4-6):158-161.
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