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题名: Rhodium-Catalyzed Direct Alkenylation and Arylation of Arene C-H Bonds via Decarbonylation of Cinnamoyl Chlorides, Cinnamic Anhydrides, and Poly(aroyl) Chlorides
作者: Ye, Wenjing1;  Luo, Ning1;  Yu, Zhengkun1, 2
刊名: ORGANOMETALLICS
发表日期: 2010-02-22
DOI: 10.1021/om900997y
卷: 29, 期:4, 页:1049-1052
收录类别: SCI ;  IC
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Efficient regioselective direct alkenylation of benzo[h]quinoline was realized with cinnamoyl chlorides as the coupling partners via decarbonylation of the chlorides and C-H bond activation by means of [Rh(CO)(2)Cl](2) as the catalyst in refluxing o-oxlene under phosphine-free conditions. For 2-phenylpridine, [Rh(CO)(2)Cl](2) or [Rh(COD)Cl](2) efficiently promoted its direct alkenylation with cinnamic anhydrides. Polyarenes were synthesized from [Rh(COD)Cl](2)-catalyzed decarbonylative poly(arylation) of isophthaloyl dichloride, terephthaloyl dichloride, or benzene-1,3,5,-tricarbonyl chloride with benzo[h] quinoline.
关键词[WOS]: PROTON-ABSTRACTION MECHANISM ;  PYRIDINE-N-OXIDES ;  CARBOXYLIC-ACIDS ;  TERMINAL ALKYNES ;  REGIOSELECTIVE ALKENYLATION ;  SELECTIVE ALKENYLATION ;  ACTIVATION ;  FUNCTIONALIZATION ;  ARYL ;  OLEFINATION
语种: 英语
WOS记录号: WOS:000274530400044
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142253
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Ye, Wenjing,Luo, Ning,Yu, Zhengkun. Rhodium-Catalyzed Direct Alkenylation and Arylation of Arene C-H Bonds via Decarbonylation of Cinnamoyl Chlorides, Cinnamic Anhydrides, and Poly(aroyl) Chlorides[J]. ORGANOMETALLICS,2010,29(4):1049-1052.
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