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Acid-assisted catalytic oxidation of benzyl alcohol by NOx with dioxygen
Sheng, Xuebin1,2; Ma, Hong1; Chen, Chen1; Gao, Jin1; Yin, Guochuan3; Xu, Jie1
关键词Alcohol Oxidation Dioxygen Cyclic Voltammetry Nitrosonium Cation
刊名CATALYSIS COMMUNICATIONS
2010-09-25
DOI10.1016/j.catcom.2010.06.012
11期:15页:1189-1192
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]TRANSITION-METAL-FREE ; MILD CONDITIONS ; NITRIC-OXIDE ; HETEROGENEOUS SYSTEM ; MOLECULAR-OXYGEN ; NITROGEN-OXIDES ; ELECTRODES ; 1,4-DIHYDROPYRIDINES ; REDUCTION ; SULFATE
英文摘要Efficient transformation of alcohols to the corresponding aldehydes is an important process in organic synthesis and industry. In the absence of transition metal ion, an acid-activated NOx has been explored for the catalytic oxidation of benzyl alcohol. Under the optimal conditions, 95% yield of benzyl aldehyde could be achieved at room temperature with dioxygen as the terminal oxidant. The reaction mechanism was investigated through UV-visible spectrometry and cyclic voltammetry, and the key active species for oxidation have been assigned to the nitrosonium cation. (C) 2010 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000282154200006
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142255
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China
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GB/T 7714
Sheng, Xuebin,Ma, Hong,Chen, Chen,et al. Acid-assisted catalytic oxidation of benzyl alcohol by NOx with dioxygen[J]. CATALYSIS COMMUNICATIONS,2010,11(15):1189-1192.
APA Sheng, Xuebin,Ma, Hong,Chen, Chen,Gao, Jin,Yin, Guochuan,&Xu, Jie.(2010).Acid-assisted catalytic oxidation of benzyl alcohol by NOx with dioxygen.CATALYSIS COMMUNICATIONS,11(15),1189-1192.
MLA Sheng, Xuebin,et al."Acid-assisted catalytic oxidation of benzyl alcohol by NOx with dioxygen".CATALYSIS COMMUNICATIONS 11.15(2010):1189-1192.
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