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题名: UV Raman spectroscopic study on the synthesis mechanism and assembly of molecular sieves
作者: Fan, Fengtao1;  Feng, Zhaochi1;  Li, Can1
刊名: CHEMICAL SOCIETY REVIEWS
发表日期: 2010
DOI: 10.1039/c0cs00012d
卷: 39, 期:12, 页:4794-4801
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: In the past decade, UV Raman spectroscopy has become a powerful technique for the characterization of the synthesis mechanism and assembly of molecular sieves. Ultraviolet excitation avoids fluorescence that plagues visible Raman spectroscopy and concurrently enhances the Raman signal because of the short wavelength of excitation and the resonance Raman effect. The advances of UV Raman spectroscopy, UV resonance Raman spectroscopy and in situ UV Raman spectroscopy and their applications to the characterization of zeolite assembly mechanisms are provided in this tutorial review. Using UV Raman spectroscopy, the synthesis mechanism of zeolites, including the identification of primary units, assembly through key intermediates, transition metal species, and the roles of the organic templates in framework formation have been elucidated, and are discussed herein.
关键词[WOS]: ZEOLITE-A ;  AUTOCATALYTIC NUCLEATION ;  HYDROTHERMAL SYNTHESIS ;  FRAMEWORK STRUCTURES ;  MASS-SPECTROMETRY ;  TS-1 ZEOLITE ;  MFI ZEOLITE ;  CRYSTALLIZATION ;  ALUMINOPHOSPHATE ;  TITANIUM
语种: 英语
WOS记录号: WOS:000284267000019
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142264
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Fan, Fengtao,Feng, Zhaochi,Li, Can. UV Raman spectroscopic study on the synthesis mechanism and assembly of molecular sieves[J]. CHEMICAL SOCIETY REVIEWS,2010,39(12):4794-4801.
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