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题名: Pd(0)-Catalyzed Diarylation of sp(3) C-H Bond in (2-Azaaryl)methanes
作者: Song, Guoyong1;  Su, Yan1;  Gong, Xue1;  Han, Keli1;  Li, Xingwei1
刊名: ORGANIC LETTERS
发表日期: 2011-04-15
DOI: 10.1021/ol200345a
卷: 13, 期:8, 页:1968-1971
收录类别: SCI ;  IC
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A highly efficient and selective palladium-catalyzed diarylation of (2-azaaryl)methanes at the methyl group is described. Aryl chlorides proved reactive enough. A palladium eta(3)-azaallyl intermediate has been identified on the basis of DFT studies.
关键词[WOS]: CATALYZED DIRECT ARYLATION ;  CROSS-COUPLING REACTIONS ;  ALPHA-ARYLATION ;  ARYL HALIDES ;  OXIDATIVE ADDITION ;  ACTIVATION ;  CHEMISTRY ;  FUNCTIONALIZATION ;  CLEAVAGE ;  REGIOSELECTIVITY
语种: 英语
WOS记录号: WOS:000289187200019
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142303
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Song, Guoyong,Su, Yan,Gong, Xue,et al. Pd(0)-Catalyzed Diarylation of sp(3) C-H Bond in (2-Azaaryl)methanes[J]. ORGANIC LETTERS,2011,13(8):1968-1971.
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