DICP OpenIR
Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions
Wang, Lian-Yue1,2; Li, Jun1; Lv, Ying1; Zhang, Heng-Yun1; Gao, Shuang1
KeywordAerobic Oxidation Alcohols Pdcl2 Nanoparticles n N-dimethylacetamide
Source PublicationJOURNAL OF ORGANOMETALLIC CHEMISTRY
2011-10-01
DOI10.1016/j.jorganchem.2011.07.019
Volume696Issue:20Pages:3257-3263
Indexed BySCI ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Inorganic & Nuclear ; Chemistry, Organic
WOS Research AreaChemistry
WOS KeywordCROSS-COUPLING REACTIONS ; MOLECULAR-OXYGEN ; TERMINAL OLEFINS ; PALLADIUM ; WATER ; CONVERSIONS ; KETONES ; GREEN ; CONVENIENT ; COMPLEXES
AbstractA new and simple PdCl2/DMA catalytic system for the alcohol oxidation has been developed using molecular oxygen as the sole oxidant under mild conditions. The catalytic system could be reused for three runs without significant loss of catalytic activity. A variety of active and non-active alcohols were oxidized to their corresponding carbonyl compounds in good to excellent yields. Gas-uptake kinetics for the catalytic system was also investigated. The ca. 1:1 molar ratio of O-2 uptake to product yield is observed, suggesting the in situ formation of H2O2. (C) 2011 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000293999500019
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142376
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Wang, Lian-Yue,Li, Jun,Lv, Ying,et al. Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2011,696(20):3257-3263.
APA Wang, Lian-Yue,Li, Jun,Lv, Ying,Zhang, Heng-Yun,&Gao, Shuang.(2011).Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions.JOURNAL OF ORGANOMETALLIC CHEMISTRY,696(20),3257-3263.
MLA Wang, Lian-Yue,et al."Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions".JOURNAL OF ORGANOMETALLIC CHEMISTRY 696.20(2011):3257-3263.
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