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题名: Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions
作者: Wang, Lian-Yue1, 2;  Li, Jun1;  Lv, Ying1;  Zhang, Heng-Yun1;  Gao, Shuang1
关键词: Aerobic oxidation ;  Alcohols ;  PdCl2 ;  N,N-dimethylacetamide ;  Nanoparticles
刊名: JOURNAL OF ORGANOMETALLIC CHEMISTRY
发表日期: 2011-10-01
DOI: 10.1016/j.jorganchem.2011.07.019
卷: 696, 期:20, 页:3257-3263
收录类别: SCI ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A new and simple PdCl2/DMA catalytic system for the alcohol oxidation has been developed using molecular oxygen as the sole oxidant under mild conditions. The catalytic system could be reused for three runs without significant loss of catalytic activity. A variety of active and non-active alcohols were oxidized to their corresponding carbonyl compounds in good to excellent yields. Gas-uptake kinetics for the catalytic system was also investigated. The ca. 1:1 molar ratio of O-2 uptake to product yield is observed, suggesting the in situ formation of H2O2. (C) 2011 Elsevier B.V. All rights reserved.
关键词[WOS]: CROSS-COUPLING REACTIONS ;  MOLECULAR-OXYGEN ;  TERMINAL OLEFINS ;  PALLADIUM ;  WATER ;  CONVERSIONS ;  KETONES ;  GREEN ;  CONVENIENT ;  COMPLEXES
语种: 英语
WOS记录号: WOS:000293999500019
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142376
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Wang, Lian-Yue,Li, Jun,Lv, Ying,et al. Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2011,696(20):3257-3263.
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