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Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions
Wang, Lian-Yue1,2; Li, Jun1; Lv, Ying1; Zhang, Heng-Yun1; Gao, Shuang1
关键词Aerobic Oxidation Alcohols Pdcl2 Nanoparticles n N-dimethylacetamide
刊名JOURNAL OF ORGANOMETALLIC CHEMISTRY
2011-10-01
DOI10.1016/j.jorganchem.2011.07.019
696期:20页:3257-3263
收录类别SCI ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear ; Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]CROSS-COUPLING REACTIONS ; MOLECULAR-OXYGEN ; TERMINAL OLEFINS ; PALLADIUM ; WATER ; CONVERSIONS ; KETONES ; GREEN ; CONVENIENT ; COMPLEXES
英文摘要A new and simple PdCl2/DMA catalytic system for the alcohol oxidation has been developed using molecular oxygen as the sole oxidant under mild conditions. The catalytic system could be reused for three runs without significant loss of catalytic activity. A variety of active and non-active alcohols were oxidized to their corresponding carbonyl compounds in good to excellent yields. Gas-uptake kinetics for the catalytic system was also investigated. The ca. 1:1 molar ratio of O-2 uptake to product yield is observed, suggesting the in situ formation of H2O2. (C) 2011 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000293999500019
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142376
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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GB/T 7714
Wang, Lian-Yue,Li, Jun,Lv, Ying,et al. Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2011,696(20):3257-3263.
APA Wang, Lian-Yue,Li, Jun,Lv, Ying,Zhang, Heng-Yun,&Gao, Shuang.(2011).Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions.JOURNAL OF ORGANOMETALLIC CHEMISTRY,696(20),3257-3263.
MLA Wang, Lian-Yue,et al."Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions".JOURNAL OF ORGANOMETALLIC CHEMISTRY 696.20(2011):3257-3263.
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