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题名: Regio- and Stereoselective Synthesis of Multisubstituted Olefins and Conjugate Dienes by Using alpha-Oxo Ketene Dithioacetals as the Building Blocks
作者: Jin, Weiwei1;  Du, Wangming1;  Yang, Qin1;  Yu, Haifeng1;  Chen, Jiping1;  Yu, Zhengkun1, 2
刊名: ORGANIC LETTERS
发表日期: 2011-08-19
DOI: 10.1021/ol201620g
卷: 13, 期:16, 页:4272-4275
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: An efficient palladium(0)-catalyzed, Cu(I)-mediated synthetic route to trisubstituted olefins and conjugate dienes has been developed via oxo directing Liebeskind-Srogl cross-coupling reactions of gem-dihaloolefin-type alpha-oxo ketene dithioacetals with aryl and alkenylboronic acids. The synthetic protocol has demonstrated rare examples of transition-metal-promoted transformations of ketene dithioacetals, providing a novel route to highly functionalized conjugate dienes.
关键词[WOS]: CROSS-COUPLING REACTIONS ;  BOND-FORMING REACTIONS ;  EFFICIENT SYNTHESIS ;  FACILE SYNTHESIS ;  AMBIENT-TEMPERATURE ;  PEPTIDYL KETONES ;  ALKENES ;  DERIVATIVES ;  ANNULATION ;  CONSTRUCTION
语种: 英语
WOS记录号: WOS:000293759100031
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142378
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Jin, Weiwei,Du, Wangming,Yang, Qin,et al. Regio- and Stereoselective Synthesis of Multisubstituted Olefins and Conjugate Dienes by Using alpha-Oxo Ketene Dithioacetals as the Building Blocks[J]. ORGANIC LETTERS,2011,13(16):4272-4275.
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