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Synthesis, Structure, and Photo luminescent Properties of Metal-Organic Coordination Polymers Assembled with Bithiophenedicarboxylic Acid
Zhao, Jiao1,2; Wang, Xiu-Li1,2; Shi, Xin3; Yang, Qi-Hua1; Li, Can1
Source PublicationINORGANIC CHEMISTRY
2011-04-18
DOI10.1021/ic101112b
Volume50Issue:8Pages:3198-3205
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Inorganic & Nuclear
WOS Research AreaChemistry
WOS KeywordSINGLE-CRYSTAL ; FRAMEWORK ; PHOTOLUMINESCENT ; FLUORESCENCE ; ZINC(II) ; MOFS ; 2D
AbstractFour novel metal organic coordination polymers with the formulas Mn-3(btdc)(3)(DMF)(4) (1), Co(btdc)-(DMF)(3) (2), Zn(btdc)(DMF)(3) (3), and Zn(btdc)(4,4'-bpy)(0.5) (4), where H(2)btdc = 2,2'-bithiophene-5,5'-dicarboxylic acid, DMF = N,N'-dimethylformamide, and 4,4'-bpy = 4,4'-bipyridine, have been successfully synthesized. Crystal 1 with Mn2+ as the cation features a three-dimensional (3D) infinite framework built from trimanganese clusters, and crystals 2 and 3 with Co2+ and Zn2+, respectively, as the cation both have one-dimensional zigzag polymeric coordination chains. Crystal 4 synthesized using a mixture of 4,4'-bpy and H(2)btdc exhibits a triply interpenetrating 3D framework built from a dizinc paddlewheel second building unit with a distorted primitive cubic single net. The results of UV/vis spectra indicate that metal binding does not disturb the detailed electronic structure of the ligand. We also demonstrate that Zn2+ can greatly enhance the luminescence emission of the H(2)btdc ligand, and the emission intensity of crystal 4 is almost 20 times higher than that of the free H(2)btdc ligand. Steady-state and time-resolved spectroscopic measurement reveal that the more rigid environment of the btdc ligand can stabilize the highly excited long-lived states in metal-organic frameworks (MOFs), which thus greatly changes the emission properties of MOFs.
Language英语
WOS IDWOS:000290457700008
Citation statistics
Cited Times:69[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142395
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Liaoning Normal Univ, Dept Chem & Chem Engn, Inst Chem Functionalized Mat, Dalian 116029, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Jiao,Wang, Xiu-Li,Shi, Xin,et al. Synthesis, Structure, and Photo luminescent Properties of Metal-Organic Coordination Polymers Assembled with Bithiophenedicarboxylic Acid[J]. INORGANIC CHEMISTRY,2011,50(8):3198-3205.
APA Zhao, Jiao,Wang, Xiu-Li,Shi, Xin,Yang, Qi-Hua,&Li, Can.(2011).Synthesis, Structure, and Photo luminescent Properties of Metal-Organic Coordination Polymers Assembled with Bithiophenedicarboxylic Acid.INORGANIC CHEMISTRY,50(8),3198-3205.
MLA Zhao, Jiao,et al."Synthesis, Structure, and Photo luminescent Properties of Metal-Organic Coordination Polymers Assembled with Bithiophenedicarboxylic Acid".INORGANIC CHEMISTRY 50.8(2011):3198-3205.
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