中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Epoxidation of olefins with O-2 and isobutyraldehyde catalyzed by cobalt (II)-containing zeolitic imidazolate framework material
作者: Zhang, Aiping1, 2;  Li, Linqing3;  Li, Jun1;  Zhang, Yi1;  Gao, Shuang1
关键词: Metal-organic frameworks ;  Zeolitic imidazolate frameworks ;  Molecular oxygen ;  Isobutyraldehyde ;  Epoxidation
刊名: CATALYSIS COMMUNICATIONS
发表日期: 2011-07-26
DOI: 10.1016/j.catcom.2011.04.013
卷: 12, 期:13, 页:1183-1187
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Co-containing zeolitic imidazolate framework material (Co-ZIF) was prepared and its catalytic performance in the aerobic epoxidation of olefins using isobutyraldehyde as reductant under mild conditions was first studied. Co-ZIF was characterized by XRD, FT-IR and X-ray single-crystal diffraction. It showed good performance in the epoxidation of olefins, with 100% conversion, 98.5% selectivity and 638.3 turnover frequency for the epoxidation of cyclooctene. Co-ZIF could be reused for 5 times without loss of its catalytic activity and the structure of the recovered catalyst was almost unchanged compared to that of the fresh one. (C) 2011 Elsevier B.V. All rights reserved.
关键词[WOS]: HYDROGEN-PEROXIDE ;  MOLECULAR-OXYGEN ;  STYRENE OXIDE ;  COMPLEXES ;  OXIDATION ;  DIOXYGEN ;  ALKENES
语种: 英语
WOS记录号: WOS:000292950000002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142402
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Dalian Polytech Univ, Dalian 116034, Peoples R China

Recommended Citation:
Zhang, Aiping,Li, Linqing,Li, Jun,et al. Epoxidation of olefins with O-2 and isobutyraldehyde catalyzed by cobalt (II)-containing zeolitic imidazolate framework material[J]. CATALYSIS COMMUNICATIONS,2011,12(13):1183-1187.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Zhang, Aiping]'s Articles
 [Li, Linqing]'s Articles
 [Li, Jun]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Zhang, Aiping]‘s Articles
 [Li, Linqing]‘s Articles
 [Li, Jun]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace