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Epoxidation of olefins with O-2 and isobutyraldehyde catalyzed by cobalt (II)-containing zeolitic imidazolate framework material
Zhang, Aiping1,2; Li, Linqing3; Li, Jun1; Zhang, Yi1; Gao, Shuang1
KeywordMetal-organic Frameworks Zeolitic Imidazolate Frameworks Molecular Oxygen Isobutyraldehyde Epoxidation
Source PublicationCATALYSIS COMMUNICATIONS
2011-07-26
DOI10.1016/j.catcom.2011.04.013
Volume12Issue:13Pages:1183-1187
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordHYDROGEN-PEROXIDE ; MOLECULAR-OXYGEN ; STYRENE OXIDE ; COMPLEXES ; OXIDATION ; DIOXYGEN ; ALKENES
AbstractCo-containing zeolitic imidazolate framework material (Co-ZIF) was prepared and its catalytic performance in the aerobic epoxidation of olefins using isobutyraldehyde as reductant under mild conditions was first studied. Co-ZIF was characterized by XRD, FT-IR and X-ray single-crystal diffraction. It showed good performance in the epoxidation of olefins, with 100% conversion, 98.5% selectivity and 638.3 turnover frequency for the epoxidation of cyclooctene. Co-ZIF could be reused for 5 times without loss of its catalytic activity and the structure of the recovered catalyst was almost unchanged compared to that of the fresh one. (C) 2011 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000292950000002
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142402
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Dalian Polytech Univ, Dalian 116034, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Aiping,Li, Linqing,Li, Jun,et al. Epoxidation of olefins with O-2 and isobutyraldehyde catalyzed by cobalt (II)-containing zeolitic imidazolate framework material[J]. CATALYSIS COMMUNICATIONS,2011,12(13):1183-1187.
APA Zhang, Aiping,Li, Linqing,Li, Jun,Zhang, Yi,&Gao, Shuang.(2011).Epoxidation of olefins with O-2 and isobutyraldehyde catalyzed by cobalt (II)-containing zeolitic imidazolate framework material.CATALYSIS COMMUNICATIONS,12(13),1183-1187.
MLA Zhang, Aiping,et al."Epoxidation of olefins with O-2 and isobutyraldehyde catalyzed by cobalt (II)-containing zeolitic imidazolate framework material".CATALYSIS COMMUNICATIONS 12.13(2011):1183-1187.
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