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One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)
Li, Dongzhen1; Wang, Yang1; Zhang, Wen-Xiong1,2; Zhang, Shaoguang1; Guang, Jie1; Xi, Zhenfeng1
Source PublicationORGANOMETALLICS
2011-10-10
DOI10.1021/om2006613
Volume30Issue:19Pages:5278-5283
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Inorganic & Nuclear ; Chemistry, Organic
WOS Research AreaChemistry
WOS KeywordEARTH-METAL COMPLEXES ; EFFICIENT MULTICOMPONENT REACTIONS ; COORDINATION CHEMISTRY ; CATALYTIC ADDITION ; IONIC LIQUIDS ; SUBSTITUTED GUANIDINES ; N-H ; STRUCTURAL-CHARACTERIZATION ; ORGANIC-SYNTHESIS ; TERMINAL ALKYNES
AbstractThe first synthesis of trisubstituted guanidinium triflates has been achieved by a simple one-step procedure from readily available amines, carbodiimides, and Zn(OTf)(2). X-ray analysis revealed they adopt 1-D chain-like or novel 3-D hydrogen-bonded networks, which have not been reported previously in the solid structure of guanidinium salts. Isolation of a binuclear zinc complex and its subsequent carbodiimide insertion provide the insight into the mechanism for the formation of guanidinium triflates.
Language英语
WOS IDWOS:000295347600025
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142438
Collection中国科学院大连化学物理研究所
Affiliation1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
2.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
Recommended Citation
GB/T 7714
Li, Dongzhen,Wang, Yang,Zhang, Wen-Xiong,et al. One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)[J]. ORGANOMETALLICS,2011,30(19):5278-5283.
APA Li, Dongzhen,Wang, Yang,Zhang, Wen-Xiong,Zhang, Shaoguang,Guang, Jie,&Xi, Zhenfeng.(2011).One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2).ORGANOMETALLICS,30(19),5278-5283.
MLA Li, Dongzhen,et al."One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)".ORGANOMETALLICS 30.19(2011):5278-5283.
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