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题名: One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)
作者: Li, Dongzhen1;  Wang, Yang1;  Zhang, Wen-Xiong1, 2;  Zhang, Shaoguang1;  Guang, Jie1;  Xi, Zhenfeng1
刊名: ORGANOMETALLICS
发表日期: 2011-10-10
DOI: 10.1021/om2006613
卷: 30, 期:19, 页:5278-5283
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: The first synthesis of trisubstituted guanidinium triflates has been achieved by a simple one-step procedure from readily available amines, carbodiimides, and Zn(OTf)(2). X-ray analysis revealed they adopt 1-D chain-like or novel 3-D hydrogen-bonded networks, which have not been reported previously in the solid structure of guanidinium salts. Isolation of a binuclear zinc complex and its subsequent carbodiimide insertion provide the insight into the mechanism for the formation of guanidinium triflates.
关键词[WOS]: EARTH-METAL COMPLEXES ;  EFFICIENT MULTICOMPONENT REACTIONS ;  COORDINATION CHEMISTRY ;  CATALYTIC ADDITION ;  IONIC LIQUIDS ;  SUBSTITUTED GUANIDINES ;  N-H ;  STRUCTURAL-CHARACTERIZATION ;  ORGANIC-SYNTHESIS ;  TERMINAL ALKYNES
语种: 英语
WOS记录号: WOS:000295347600025
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142438
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
2.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

Recommended Citation:
Li, Dongzhen,Wang, Yang,Zhang, Wen-Xiong,et al. One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)[J]. ORGANOMETALLICS,2011,30(19):5278-5283.
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