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Study on collisional deactivation of O-2((1)Delta(g)) by H-2 and D-2
Du, Shuyan; Leng, Jing; Wang, Junhui; Yang, Heping; Sha, Guohe; Zhang, Cunhao
关键词Singlet Oxygen Collisional Deactivation Hydrogen Deuterium
刊名CHEMICAL PHYSICS
2011-05-26
DOI10.1016/j.chemphys.2011.04.012
383期:1-3页:83-85
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]SINGLET OXYGEN ; SOLVENT MOLECULES ; SPECTROSCOPY ; O2(A1DELTAG)
英文摘要The deactivation rate constants of O-2((1)Delta(g)) by H-2 and D-2 are respectively measured to be 3.91 +/- 0.12 x 10(-18) cm(3) s(-1) and 1.1 +/- 0.3 x 10(-19) cm(3) s(-1), which agree well with the quantum mechanical calculation by Kustrev. Their deactivation mechanisms by H-2 and D-2 are analyzed according to the E-V energy transfer model developed by Schmidt, indicating that the main deactivation channel for H-2 is O-2((1)Delta(g), v = 0 --> (3)Sigma(-)(g), v '' = 0) and H-2 (Delta v = 2), while that for D-2 is O-2((1)Delta(g), v' = 0 --> (3)Sigma(-)(g), v '' = 1) and D-20 (Delta v = 2), which entirely matches the calculation by Kustrev. (C) 2011 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000291027600011
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142492
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
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Du, Shuyan,Leng, Jing,Wang, Junhui,et al. Study on collisional deactivation of O-2((1)Delta(g)) by H-2 and D-2[J]. CHEMICAL PHYSICS,2011,383(1-3):83-85.
APA Du, Shuyan,Leng, Jing,Wang, Junhui,Yang, Heping,Sha, Guohe,&Zhang, Cunhao.(2011).Study on collisional deactivation of O-2((1)Delta(g)) by H-2 and D-2.CHEMICAL PHYSICS,383(1-3),83-85.
MLA Du, Shuyan,et al."Study on collisional deactivation of O-2((1)Delta(g)) by H-2 and D-2".CHEMICAL PHYSICS 383.1-3(2011):83-85.
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