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Photoelectron Imaging of AgOCH3- and Ag-(CH3OH)(x) (x=1, 2)
Chi, Chao-xian2; Xie, Hua1; Cong, Ran1; Tang, Zi-chao1; Zhou, Ming-fei2
KeywordSilver Methanol Complex Solvation Photoelectron Imaging Density Functional Calculation
Source PublicationCHINESE JOURNAL OF CHEMICAL PHYSICS
2011-10-01
DOI10.1088/1674-0068/24/05/557-562
Volume24Issue:5Pages:557-562
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectPhysics, Atomic, Molecular & Chemical
WOS Research AreaPhysics
WOS KeywordEFFECTIVE CORE POTENTIALS ; LIQUID METHANOL ; GAS-PHASE ; AB-INITIO ; VIBRATIONAL SPECTROSCOPY ; MOLECULAR CALCULATIONS ; SOLVATION DYNAMICS ; ELECTRON-AFFINITIES ; DILUTE-SOLUTIONS ; HCL SOLVATION
AbstractThe AgOCH3- and Ag-(CH3OH)(x) (x=1, 2) anions are studied by photoelectron imaging as well as ab initio calculations. The adiabatic and vertical detachment energies (ADE and VDE) of AgOCH3- are determined as 1.29(2) and 1.34(2) eV, respectively, from the vibrational resolved photoelectron spectrum. The Ag-(CH3OH)1,2 anionic complexes are characterized as metal atomic anion solvated by the CH3OH molecules with the electron mainly localized on the metal. The photoelectron spectra of Ag-(CH3OH)(x) (x=0, 1, 2) show a gradual increase in VDE with increasing x, due to the solvent stabilization. Evidence for the methanol-methanol hydrogen bonding interactions appears when the Ag- is solvated by two methanol molecules.
Language英语
WOS IDWOS:000297139200009
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142527
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
2.Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysts & Innovat Mat, Shanghai 200433, Peoples R China
Recommended Citation
GB/T 7714
Chi, Chao-xian,Xie, Hua,Cong, Ran,et al. Photoelectron Imaging of AgOCH3- and Ag-(CH3OH)(x) (x=1, 2)[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2011,24(5):557-562.
APA Chi, Chao-xian,Xie, Hua,Cong, Ran,Tang, Zi-chao,&Zhou, Ming-fei.(2011).Photoelectron Imaging of AgOCH3- and Ag-(CH3OH)(x) (x=1, 2).CHINESE JOURNAL OF CHEMICAL PHYSICS,24(5),557-562.
MLA Chi, Chao-xian,et al."Photoelectron Imaging of AgOCH3- and Ag-(CH3OH)(x) (x=1, 2)".CHINESE JOURNAL OF CHEMICAL PHYSICS 24.5(2011):557-562.
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