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Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations
Zhao, Yu-Chao; Yuan, Jinyun; Zhang, Zeng-Guang; Xu, Hong-Guang; Zheng, Weijun
刊名DALTON TRANSACTIONS
2011
DOI10.1039/c0dt01179g
40期:11页:2502-2508
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear
研究领域[WOS]Chemistry
关键词[WOS]TRANSITION-METAL SULFIDES ; SULFUR CLUSTER IONS ; GAS-PHASE ; INFRARED-SPECTRA ; LASER-ABLATION ; PHOTOELECTRON-SPECTROSCOPY ; PHOTOGRAPHIC PROCESS ; ELECTRONIC-STRUCTURE ; REACTIVITY ; MOLECULES
英文摘要Manganese polysulfide cations, MnS(x)(+) (x = 1-10), were studied with mass-selected photodissociation experiments and density functional calculations. We found that MnS(+), MnS(2)(+) and MnS(3)(+) undergo dissociation at 355 nm by loss of S, S(2) and S(3), respectively. The dissociation of larger clusters is relatively complex because of the existence of multiple isomers and multiple dissociation channels. The geometric structures of the low-lying isomers found by theoretical calculations are consistent with the dissociation channels observed in the experiments. The dissociation of MnS(x)(+) clusters occurs mainly by breaking of the Mn-S bonds since they are weaker than the S-S bonds.
语种英语
WOS记录号WOS:000288030500014
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142568
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China
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Zhao, Yu-Chao,Yuan, Jinyun,Zhang, Zeng-Guang,et al. Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations[J]. DALTON TRANSACTIONS,2011,40(11):2502-2508.
APA Zhao, Yu-Chao,Yuan, Jinyun,Zhang, Zeng-Guang,Xu, Hong-Guang,&Zheng, Weijun.(2011).Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations.DALTON TRANSACTIONS,40(11),2502-2508.
MLA Zhao, Yu-Chao,et al."Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations".DALTON TRANSACTIONS 40.11(2011):2502-2508.
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