中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations
作者: Zhao, Yu-Chao1;  Yuan, Jinyun1;  Zhang, Zeng-Guang1;  Xu, Hong-Guang1;  Zheng, Weijun1
刊名: DALTON TRANSACTIONS
发表日期: 2011
DOI: 10.1039/c0dt01179g
卷: 40, 期:11, 页:2502-2508
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear
研究领域[WOS]: Chemistry
英文摘要: Manganese polysulfide cations, MnS(x)(+) (x = 1-10), were studied with mass-selected photodissociation experiments and density functional calculations. We found that MnS(+), MnS(2)(+) and MnS(3)(+) undergo dissociation at 355 nm by loss of S, S(2) and S(3), respectively. The dissociation of larger clusters is relatively complex because of the existence of multiple isomers and multiple dissociation channels. The geometric structures of the low-lying isomers found by theoretical calculations are consistent with the dissociation channels observed in the experiments. The dissociation of MnS(x)(+) clusters occurs mainly by breaking of the Mn-S bonds since they are weaker than the S-S bonds.
关键词[WOS]: TRANSITION-METAL SULFIDES ;  SULFUR CLUSTER IONS ;  GAS-PHASE ;  INFRARED-SPECTRA ;  LASER-ABLATION ;  PHOTOELECTRON-SPECTROSCOPY ;  PHOTOGRAPHIC PROCESS ;  ELECTRONIC-STRUCTURE ;  REACTIVITY ;  MOLECULES
语种: 英语
WOS记录号: WOS:000288030500014
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142568
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China

Recommended Citation:
Zhao, Yu-Chao,Yuan, Jinyun,Zhang, Zeng-Guang,et al. Structures of manganese polysulfides: mass-selected photodissociation and density functional calculations[J]. DALTON TRANSACTIONS,2011,40(11):2502-2508.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Zhao, Yu-Chao]'s Articles
 [Yuan, Jinyun]'s Articles
 [Zhang, Zeng-Guang]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Zhao, Yu-Chao]‘s Articles
 [Yuan, Jinyun]‘s Articles
 [Zhang, Zeng-Guang]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace