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Silyl-substituted 1,3-butadienes for Diels-Alder reaction, ene reaction and allylation reaction
Zhao, Fei; Zhang, Shaoguang; Xi, Zhenfeng
刊名CHEMICAL COMMUNICATIONS
2011
DOI10.1039/c0cc05665k
47期:15页:4348-4357
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]BASE CHROMIUM(III) COMPLEXES ; METAL-PROMOTED CYCLIZATION ; TANDEM ALDOL-ALLYLATION ; ORGANIC-SYNTHESIS ; INTRAMOLECULAR ALLYLATION ; STEREOSELECTIVE-SYNTHESIS ; CONJUGATED DIENES ; COUPLING REACTIONS ; CONVENIENT METHOD ; ENOL ETHERS
英文摘要Silyl-substituted 1,3-butadienes are useful building blocks and are readily applied in several types of reactions such as Diels-Alder reaction, ene reaction and allylation. They can also participate in different tandem reactions such as Diels-Alder/allylation, ene/allylation, ene/allylation/Diels-Alder reaction, ene/allylation/ene reaction and ene/allylation/Diels-Alder/allylation reaction. This feature article reviews the synthesis of silyl-substituted 1,3-butadienes, and their applications in the reaction types mentioned above, involving a tandem Diels-Alder/ene/allylation process. This article also introduces some reactions of alkenylsilanes and allylsilanes for comparison and discussion about the tandem reaction. The tandem reactions described in this article are a powerful tool to construct complicated multicyclic compounds with high selectivity and high efficiency.
语种英语
WOS记录号WOS:000288866300003
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142575
专题中国科学院大连化学物理研究所
作者单位Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
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GB/T 7714
Zhao, Fei,Zhang, Shaoguang,Xi, Zhenfeng. Silyl-substituted 1,3-butadienes for Diels-Alder reaction, ene reaction and allylation reaction[J]. CHEMICAL COMMUNICATIONS,2011,47(15):4348-4357.
APA Zhao, Fei,Zhang, Shaoguang,&Xi, Zhenfeng.(2011).Silyl-substituted 1,3-butadienes for Diels-Alder reaction, ene reaction and allylation reaction.CHEMICAL COMMUNICATIONS,47(15),4348-4357.
MLA Zhao, Fei,et al."Silyl-substituted 1,3-butadienes for Diels-Alder reaction, ene reaction and allylation reaction".CHEMICAL COMMUNICATIONS 47.15(2011):4348-4357.
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