中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Pd-Catalyzed Asymmetric Hydrogenation of C=C Bond of alpha,beta-Unsaturated Ketones
作者: Wang, Duo-Sheng1;  Wang, Da-Wei1;  Zhou, Yong-Gui1, 2
关键词: palladium ;  hydrogenation ;  unsaturated ketones ;  SDP ligand
刊名: SYNLETT
发表日期: 2011-04-01
DOI: 10.1055/s-0030-1259725
期: 7, 页:947-950
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Homogenous palladium-catalyzed asymmetric hydrogenation of C=C double bond of alpha,beta-unsaturated ketones has been developed by using palladium(II) trifluoroacetate/(S)-7,7'-bis[ di(4-methoxyphenyl]phosphino)-1,1'-spirobiindane complex [Pd(OCOCF(3))(2)-(S)-An-SDP] as the catalyst under ambient hydrogen pressure and room temperature with up to 89% ee.
关键词[WOS]: BETA-UNSATURATED-KETONES ;  HIGHLY ENANTIOSELECTIVE HYDROGENATION ;  DYNAMIC KINETIC RESOLUTION ;  CHIRAL PALLADIUM CATALYSTS ;  SPIRO DIPHOSPHINES ;  PHOSPHORUS LIGANDS ;  ALLYLIC ALCOHOLS ;  ALPHA ;  COMPLEXES ;  IMINES
语种: 英语
WOS记录号: WOS:000289411900018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142588
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Wang, Duo-Sheng,Wang, Da-Wei,Zhou, Yong-Gui. Pd-Catalyzed Asymmetric Hydrogenation of C=C Bond of alpha,beta-Unsaturated Ketones[J]. SYNLETT,2011(7):947-950.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Wang, Duo-Sheng]'s Articles
 [Wang, Da-Wei]'s Articles
 [Zhou, Yong-Gui]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Wang, Duo-Sheng]‘s Articles
 [Wang, Da-Wei]‘s Articles
 [Zhou, Yong-Gui]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace